1637-65-6

Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 106-37-6 1.4-dibromobenzene 
• 17903-34-3 4-bromophenyl(dimethyl)(ethoxy)silane 
• 22480-64-4 4-bromophenyllithium 

Downstream Products

• 127472-89-3 C₂₀H₄₈Si₇ 
• 144752-33-0 1-(4-Dimethylsilanyl-phenyl)-1,1,2,2-tetramethyl-2-phenyl-disilane 
• 127472-88-2 1-Chlor-6-<4-(chlordimethylsilyl)phenyl>-1,1,2,2,3,3,4,4,5,5,6,6-dodecamethylhexasilan 
• 861857-11-6 bis(p-dimethylsilylphenyl)dimethylstannane 
• 129731-03-9 p-dimethylsilylbenzaldehyde 
• 13315-17-8 4,4'-bis(dimethylsilyl)diphenyl ether 
• 106-41-2 4-bromo-phenol 
• 17021-92-0 (4-bromophenyl)(methoxy)dimethylsilane 
• 861857-10-5 bis(p-dimethylsilylphenyl)dimethylgermane 

Relevant academic research and scientific papers

METHOD FOR PRODUCING SURFACE-MODIFIED BASE MATERIAL, METHOD FOR PRODUCING JOINED BODY, NEW HYDROSILANE COMPOUND, SURFACE TREATMENT AGENT, SURFACE TREATMENT AGENT KIT, AND SURFACE-MODIFIED BASE MATERIAL

The method for producing a surface-modified base material according to the present invention includes a step of bringing a base material having a polar group present on a surface thereof into contact with a hydrosilane compound having a molecular structure A and having a Si—H group composed of a silicon atom of the molecular structure A and a hydrogen atom bonded to the silicon atom in the presence of a borane catalyst so as to allow a dehydrocondensation reaction to take place between the base material and the compound, thereby forming the base material surface-modified with the molecular structure A. This production method is capable of surface-modifying a base material at a lower temperature in a shorter time than conventional methods and allows a wide variety of options for the form, type, and application of the base material, the mode of the modification reaction, and the type of the molecular structure with which the base material is surface-modified.

Ru(ii)-Pheox-catalyzed Si-H insertion reaction: construction of enantioenriched carbon and silicon centers

We established a highly enantioselective Si-H insertion reaction to construct chiral centers at the carbon and silicon atoms, using a Ru(ii)-pheox catalyst. The catalytic asymmetric Si-H insertion reaction of α-methyl-α-diazoesters proceeded smoothly with excellent stereoinduction at both the neighboring carbon and silicon atoms (up to 99% yield and 99% ee).

NOVEL SYNTHESIS METHOD OF SILANE COMPOUND FOR PACKAGING OPTICAL DEVICES

The present invention relates to a novel synthesis method of a silane compound, and more specifically, to a method for manufacturing a silane compound with the amount of impurities minimized by using an Ullmann-type reaction instead of a conventional Girg

Synthesis of phenols via fluoride-free oxidation of arylsilanes and arylmethoxysilanes

Rapid, efficient methods have been developed to prepare phenols from the oxidation of arylhydrosilanes. The effects of arene substituents and fluoride promoters on this process show that while electron-deficient arenes can undergo direct oxidation from the hydrosilane, electron-rich aromatics benefit from silane activation via oxidation to the methoxysilane using homogeneous or heterogeneous transition metal catalysis. The combination of these two oxidations into a streamlined flow procedure involving minimal processing of reaction intermediates is also reported.

Silicon-carbon unsaturated compounds XLIV. Photochemical behavior of permethylated p-(disilanylene)phenylene oligomers

The p-(disilanylene)phenylene oligomers, Me3Si(Me2Si-C6H4-SiMe2)nSiMe3 with n = 2-4 (2, 3, and 4) were prepared and their photochemical behavior was investigated in a benzene solution.Photolysis of 2 in the presence of isobutene afforded 1-isobutyldimethy

Convenient route to di- and triorganosilyl ethyl ethers and the corresponding di- and triorganosilanes

Tetraethoxysilane was treated with alkyl- and aryllithium reagents for the reparation of organosilyl ethyl ethers of the type R3SiOEt, R2R'SiOEt, and R2Si(OEt)2, that can be reduced to the organosilanes R3SiH, R2R'SiH, and R2SiH2, respectively, Compounds of the type RR'R''SiOEt cannot be cleanly formed.The reduction procedure involves treatment of the silyl alkoxy ethers with diisobutylaluminium hydride (DIBALH) and hydrolysis of the remaining alkylaluminium compounds with Na2SO4*10H2O.This hydrolysis provides a convenient method for the isolation of R3SiH, R2R'SiH, and R2SiH2 compounds without hydrolysis of the Si-H moiety that often occurs in standard aqueous work-up procedures of unhindered silanes.