16390-58-2

Upstream product

• 56-23-5 tetrachloromethane 
• 16390-61-7 1-phenyl-1,2-closo-C₂B₁₀H₁₁ 
• 67-66-3 chloroform 
• 23777-83-5 2-chloro decaborane⁽¹⁴⁾ 
• 23777-82-4 1-chloro decaborane⁽¹⁴⁾ 
• 536-74-3 phenylacetylene 
• 7782-50-5 chlorine 
• 87-90-1 trichloroisocyanuric acid 

Relevant academic research and scientific papers

Practical Synthesis of B(9)-Halogenated Carboranes with N-Haloamides in Hexafluoroisopropanol

The B(9)-H halogenation of o-carborane and m-carborane was achieved with excellent selectivities in hexafluoroisopropanol (HFIP) under simple reaction conditions: single reagent [trichloroisocyanuric acid (TCCA), tribromoisocyanuric acid (TBCA) or N-iodosuccinimide (NIS)], catalyst-free, air-/moisture-tolerant, and convenient work-up. With this method, a variety of 9-halogenated o-carboranes and m-carboranes were obtained in good to excellent yields with broad tolerance of functional groups.