16411-17-9

Basic information

• Product Name: Benzene, 1-(ethenylthio)-4-methoxy-
• CAS NO: 16411-17-9
• Molecular Formula: C9H10OS
• Molecular Weight: 166.244
• Mol File: 16411-17-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(ethenylthio)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(ethenylthio)-4-methoxy-(16411-17-9)
• EPA Substance Registry System: Benzene, 1-(ethenylthio)-4-methoxy-(16411-17-9)

Safety Data

• Hazardous Substances Data: 16411-17-9(Hazardous Substances Data)

Upstream product

• 5684-31-1 2,2-dimethyl-1,3-oxathiolane 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 33735-40-9 2,2-diphenyl-1,3-oxathiolane 
• 13290-35-2 (2-bromoethyl)(4-methoxyphenyl)sulfane 
• 696-63-9 4-Methoxybenzenethiol 
• 106-93-4 ethylene dibromide 
• 74-85-1 ethene 
• 20761-70-0 1-(2-chloro-ethylsulfanyl)-4-methoxy-benzene 
• 928-57-4 2-chloroethyl thiocyanate 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 128092-50-2 (+)-(R)-Ethyl p-Methoxyphenyl Sulfoxide 
• 16191-87-0 1-(vinylsulfonyl)-4-methoxybenzene 
• 76051-31-5 3-(4-Methoxy-phenylsulfanyl)-cyclobutane-1,1,2,2-tetracarbonitrile 

Relevant articles and documents

Difluoro- and trifluoro diazoalkanes-complementary approaches in batch and flow and their application in cycloaddition reactions

Herein we report on applications of fluorinated diazoalkanes in cycloaddition reactions, with the emphasis on studying subtle differences between diverse fluorinated diazo compounds. These differences led to two major synthetic protocols in batch and flow that allow the safe and scalable synthesis of fluoroalkyl-, sulfone-substituted pyrazolines.

Hydrogenative Kinetic Resolution of Vinyl Sulfoxides

Enantiopure sulfoxides are valuable precursors of organosulfur compounds with broad application in organic and pharmaceutical chemistry. An unprecedented strategy for obtaining highly enantioenriched sulfoxides based on a hydrogenative kinetic resolution using Rh-complexes of phosphine-phosphite ligands as catalysts is reported. After optimization, highly efficient conditions for the kinetic resolution of racemic sulfoxides have been identified. This methodology has been applied to a set of racemic aralkyl or aryl vinyl sulfoxides and allowed the isolation of both recovered and reduced products in excellent yields and enantioselectivities (up to 99% and 97% ee, respectively; 16 examples).

A non-outer sphere mechanism for the ionization of aryl vinyl sulfides by triarylaminium salts

Evidence is presented that the formation of aryl vinyl sulfide cation radicals from the corresponding neutral precursors via reaction with tris(4- bromophenyl)aminium hexachloroantimonate in the context of a cation radical Diels-Alder addition to 1,3-cyclopentadiene does not occur via outer sphere electron transfer but by a mechanism involving strong covalent interaction between the aminium salt acting as an electrophile and the aryl vinyl sulfide substrate acting as a nucleophile.