16437-72-2Relevant academic research and scientific papers
Synthetic method of methylthiomethyl
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Paragraph 0104; 0105, (2019/02/06)
The invention provides a synthetic method of methylthiomethyl. The synthetic method comprises the step of carrying out crossed dehydrogenation on a carboxylic acid compound and dimethylsulfoxide in the presence of nitrogen and organic amine, so as to gene
Facile synthesis of methylthiomethyl esters through Pummerer-type rearrangement of carboxylic acids and DMSO under metal-free conditions
Wang, Shuiliang,Fu, Zhengjiang,Jiang, Yongqing,Liang, Yuxiang,Cai, Hu
supporting information, p. 950 - 958 (2019/03/17)
A green and cost-effective Pummerer-type rearrangement between readily accessible carboxylic acids and DMSO has been achieved under metal-free conditions in satisfactory to excellent yields. The transformation for the synthesis of valuable methylthiomethy
Fe2O3-catalyzed Pummerer rearrangement of acyl chlorides and sulfoxides: Facile synthesis of alkylthiomethyl ester
Xing, Haotian,Chen, Long,Jia, Yimin,Jiang, Zhongxing,Yang, Zhigang
supporting information, p. 2199 - 2202 (2017/05/16)
A simple, effective approach for the Pummerer rearrangement of acyl chlorides with sulfoxides by using a low-cost and more abundant Fe catalyst has been described. The alkylthiomethyl ester products were prepared in good to excellent yields for a range of different substrates including asymmetrical sulfoxides and acyl chlorides with a variety of functional groups under mild reaction conditions. The reaction features short reaction time, simple manipulation, cheap reagents and a broad substrate scope. Single crystal X-ray analysis of a representative methylthiomethyl (MTM) group containing product was also reported.
A simple, rapid and efficient protocol for the synthesis of methylthiomethyl esters under Swern oxidation conditions
Jadhav, Sunil B.,Ghosh, Usha
, p. 2485 - 2487 (2007/10/03)
A rapid, mild and high yielding method for the synthesis of methylthiomethyl esters is reported from the corresponding aliphatic, aromatic and unsaturated carboxylic acids under Swern oxidation conditions using dimethylsulfoxide, oxalyl chloride and triet
