16458-22-3

Basic information

• Product Name: 1-benzyl azulene
• Synonyms: 1-benzyl azulene
• CAS NO: 16458-22-3
• Molecular Weight: 218.298
• Mol File: 16458-22-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-benzyl azulene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzyl azulene(16458-22-3)
• EPA Substance Registry System: 1-benzyl azulene(16458-22-3)

Safety Data

• Hazardous Substances Data: 16458-22-3(Hazardous Substances Data)

Upstream product

• 4831-01-0 1-benzyl-2,3-dihydro-1H-indene 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 275-51-4 azulene 
• 15298-67-6 1-benzylidene-indan 
• 50603-71-9 3-methoxycarbonyl-2H-cyclohepta[b]furan-2-one 
• 2154-56-5 benzyl radical 

Downstream Products

• 93259-72-4 3-Chlor-1-benzyl-azulen 
• 100734-10-9 1-Benzyl-3-tricyanvinyl-azulen 
• 101893-87-2 1-(3-benzyl-azulen-1-yl)-ethanone 

Relevant articles and documents

First intermolecular palladium catalyzed arylation of an unfunctionalized aromatic hydrocarbon

Azulene is arylated by iodobenzene and by 4-nitro-chlorobenzene under palladium catalysis at the electron-rich 1-position.

A Versatile Synthetic Method of 1-Alkylazulenes and Azulene by the Reactions of 3-Methoxycarbonyl-2H-cycloheptafuran-2-one with in situ Generated Enamines

Methyl 3-alkylazulene-1-carboxylates were synthesized in high yields by the reaction of 3-methoxycarbonyl-2H-cycloheptafuran-2-one with in situ generated morpholine enamines of aldehydes.Treatment of the esters with 100percent phosphoric acid gave 1-alkylazulenes in excellent yields.Azulene was also synthesized in a good yield via methyl azulene-1-carboxylate with a modification of this method.