16480-57-2

Basic information

• Product Name: sodium 3-phenyl-L-alaninate
• Synonyms: sodium 3-phenyl-L-alaninate;(S)-2-Amino-3-phenylpropionic acid sodium salt;L-Phenylalanine sodium salt;Phenylalanine sodium
• CAS NO: 16480-57-2
• Molecular Formula: C₉H₁₀NO₂*Na
• Molecular Weight: 187.17097
• EINECS: 240-534-3
• Mol File: 16480-57-2.mol

Chemical Properties

• Boiling Point: 307.5°Cat760mmHg
• Flash Point: 139.8°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.000313mmHg at 25°C
• CAS DataBase Reference: sodium 3-phenyl-L-alaninate(CAS DataBase Reference)
• NIST Chemistry Reference: sodium 3-phenyl-L-alaninate(16480-57-2)
• EPA Substance Registry System: sodium 3-phenyl-L-alaninate(16480-57-2)

Safety Data

• Hazardous Substances Data: 16480-57-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H11NO2.Na/c10-8(9(11)12)6-7-4-2-1-3-5-7;/h1-5,8H,6,10H2,(H,11,12);/q;+1/p-1/t8-;/m0./s1

Upstream product

• 63-91-2 L-phenylalanine 
• 35909-92-3 N-carbobenzoxy-L-phenylalanine methyl ester 
• 75428-57-8 N-(1-Methyl-2-ethoxycarbonylvinyl)-DL-phenylalanine sodium salt 
• 55740-07-3 (4S)-4-benzyl-5-oxo-1,3-oxazolidine-3-carboxylic acid benzyl ester 

Downstream Products

• 13734-34-4 N-tert-butoxycarbonyl-L-phenylalanine 
• 118251-78-8 (+)-<(Z)-N-benzoyl-β-methyldidehydrophenylalanyl>-L-phenylalanine 
• 75428-57-8 N-(1-Methyl-2-ethoxycarbonylvinyl)-DL-phenylalanine sodium salt 
• 92812-93-6 (S)-3-Phenyl-2-(2-pyridin-4-yl-ethoxycarbonylamino)-propionic acid 
• 5002-73-3 ZGlyPheONa 
• 112914-67-7 N-<(S,S)-2,4-dibenzyl-4-carboxybutyryl>-(S)-phenylalanine disodium salt 
• 2577-90-4 methyl (2S)-2-amino-3-phenylpropanoate 
• 80639-96-9 aspirin phenylalanine 
• 23635-30-5 (S)-(-)-methyl N-(trifluoroacetyl)phenylalaninate 
• 114457-94-2 (S)-3-phenyl-2[(pyrazine-2-carbonyl)-amino]propionic acid 
• 1174715-53-7 (4S)-4-benzyl-2,2-dimethyl-3-(naphthalene-1-carbonyl)-1,3-oxazolidin-5-one 
• 3588-51-0 N-tert.-Amyloxycarbonyl-phenylalanin 

Relevant articles and documents

Bimetallic organotin(IV) complexes with ferrocene-based azomethines: Synthesis, characterization, semi-empirical study, and antibacterial activity

A series of bimetallic organotin(IV) complexes with ferrocene-based azomethines (Schiff bases) were synthesized by reacting sodium salt of tranexamic acid, 4-amino butanoic acid, and phenyl alanine with trimethyltin and tributyltin chloride in 1 : 1 molar ratio under inert atmosphere. The synthesized trialkyl organotin complexes condense with formyl ferrocene under inert atmosphere to yield organotin(IV) ferrocenyl Schiff bases. Composition of the organotin(IV) complexes, bonding behavior of donor groups, and structural assignments were studied by elemental analysis, FT-IR, 1H, 13C, 119Sn NMR, and mass spectrometry. The spectral data suggest that the ligand is bidentate, coordinating through oxygens. Spectroscopic techniques reveal distorted tetrahedral geometry in solution for the complexes. As solids, the complexes are trigonal bipyramidal, confirmed by semi-empirical study. Mass spectrometric and elemental analysis data support the solid and solution spectroscopic results. Bioactivity screenings show invitro biological potential.

Liquid fluorescent whitener and preparation method thereof

The invention relates to a liquid fluorescent whitener and a preparation method thereof, and belongs to the technical field of special assistants for printing, dyeing and papermaking. A technical problem to be solved is providing the liquid fluorescent whitener and the preparation method thereof. The effective component of the fluorescent whitener is 4,4'-bis[(4-anilino-6-Ramino acid)-1,3,5-triazinyl-2-yl)amino]stilbene-2,2'-tetrasulfonic acid tetrasodium salt, wherein R is a phenyl ring-containing amino acid group. The preparation method comprises the following steps: mixing 4,4'-diaminostilbene-2,2'-disulfonic acid with a NaOH solution to prepare a sodium 4,4'-diaminostilbene-2,2'-disulfonate solution product I, and mixing amino acids with the NaOH solution to prepare an amino acid sodium salt; adding an emulsifier, concentrated hydrochloric acid, cyanuric chloride and sodium sulfanilate to ice water, and reacting to generate a product II; adding the product I to the product II to generate a product III; and adding the amino acid sodium salt to the product III to obtain a crude whitener IV, carrying out pumping filtration, and carrying out desalting concentration to obtain the liquid fluorescent whitener.

Natural amino acid salt catalyzed aldol reactions of isatins with ketones: highly enantioselective construction of 3-alkyl-3-hydroxyindolin-2-ones

Abstract The asymmetric synthesis of 3-alkyl-3-hydroxyindolin-2-ones via direct aldol reaction of isatin with ketones catalyzed by natural amino acid salts is described, in which the phenylalanine lithium salt was found to be the best catalyst. This strategy was then applied to a variety of isatin and ketone substrates and the corresponding aldol products were obtained in excellent yields (up to 97%) with good to excellent enantioselectivities (up to 90%).

Hydration of amino acids from ultrasonic measurements

In this paper the results of compressibility of aqueous solutions of amino acids in water and in aqueous HCl and NaOH solutions at 25 °C are presented. The effect of the charged protonated amino groups and deprotonated carboxylic groups on the hydration number was tested. The idea of additivity of the hydration number with the constituents of the solute molecule was successfully applied and discussed.

NITRIC OXIDE DONATING PROSTAMIDES

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Mild regeneration of the carboxylic group of amino acid alkyl esters by aqueous methanolic sodium hydrogen carbonate via 5-oxazolidinones

A simple racemization-free procedure allows the regeneration of the carboxylic acid group of amino acid alkyl esters by way of an intermediate 5-oxazolidinone which is hydrolyzed by treatment with sodium hydrogen carbonate in aqueous methanol.