164923-33-5

Upstream product

• 2637-34-5 2-Sulfanylpyridine 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 

Downstream Products

• 168985-18-0 3,4,6-tri-O-benzyl-α-D-mannopyranosyl 2-pyridyl sulfone 
• 168212-58-6 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 168985-27-1 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 168985-19-1 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 168985-17-9 3,4,6-Tri-O-benzyl-2-O-(dimethylvinylsilyl)-α-D-mannopyranosyl 2-pyridyl sulfone 
• 421593-94-4 pyridin-2-yl 3,4,6-tri-O-benzyl-2-O-[3-(methyl-2,3-di-O-benzyl-α-D-glucopyranosid-6-yloxy)carbonylbenzo-1-yl]-1-thio-α-D-mannopyranoside 
• 421593-96-6 methyl 6,2'-O-(1,3-isophthaloyl)-(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3-di-O-benzyl-α-D-glucopyranoside 
• 421593-97-7 methyl (3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3-di-O-benzyl-α-D-glucopyranoside 
• 421593-93-3 pyridin-2-yl 2-O-(benzo-1-yl-3-carboxy)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 421593-92-2 pyridin-2-yl 2-O-(benzo-1-yl-3-chlorocarbonyl)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 164923-35-7 pyridin-2-yl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 197158-95-5 2-O-Acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl 2-pyridyl sulfone 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Relevant academic research and scientific papers

Efficient intramolecular β-mannoside formation using m-xylylene and isophthaloyl derivatives as rigid spacers

A series of mannosyl donors linked via position 2 to an m-xylylene or an isophthaloyl spacer which was connected to the position 6 of a glucoside acceptor afforded, via intramolecular glycosylation, the corresponding disaccharides with high β anomeric ratio.

1,2-cis-c-glycoside synthesis by samarium diiodide-promoted radical cyclizations

The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an