168212-58-6

Upstream product

• 125672-57-3 Chloro-dimethyl-oct-1-ynyl-silane 
• 168985-18-0 3,4,6-tri-O-benzyl-α-D-mannopyranosyl 2-pyridyl sulfone 
• 164923-33-5 pyridin-2-yl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 2637-34-5 2-Sulfanylpyridine 
• 164923-35-7 pyridin-2-yl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 629-05-0 n-octyne 

Downstream Products

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Relevant academic research and scientific papers

1,2-cis-c-glycoside synthesis by samarium diiodide-promoted radical cyclizations

The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an