168985-18-0

Upstream product

• 164923-35-7 pyridin-2-yl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 2637-34-5 2-Sulfanylpyridine 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 164923-33-5 pyridin-2-yl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 168985-27-1 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 168985-19-1 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 168212-58-6 3,4,6-Tri-O-benzyl-2-O--α-D-mannopyranosyl 2-pyridyl sulfone 
• 181506-87-6 2-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-sulfonyl]-pyridine 
• 168985-17-9 3,4,6-Tri-O-benzyl-2-O-(dimethylvinylsilyl)-α-D-mannopyranosyl 2-pyridyl sulfone 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 168212-60-0 2-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-trimethylsilanyloxy-tetrahydro-pyran-2-sulfonyl)-pyridine 
• 208102-16-3 (R)-1-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-nonan-1-ol 
• 188893-19-8 (S)-1-[(2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-nonan-1-ol 

Relevant academic research and scientific papers

1,2-cis-c-glycoside synthesis by samarium diiodide-promoted radical cyclizations

The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an