16495-77-5

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 13839-57-1 copper(I) pentafluorothiophenolate 
• 1146-44-7 4,4'-dichlorophenyl thiosulfonate 
• 1206-46-8 trimethyl(pentafluorophenyl)silane 
• 1213-40-7 S-(4-chlorophenyl)benzene thiosulfonate 
• 106-54-7 p-Chlorothiophenol 

Downstream Products

• 194853-86-6 4-fluoro-2-(trifluoromethyl)benzonitrile 
• 67515-59-7 4-Fluoro-3-(trifluoromethyl)benzonitrile 
• 144864-03-9 3-fluoro-6-phenylpyridazine 
• 62850-13-9 2-fluoro-5-phenylpyrimidine 
• 1493-45-4 2-fluoro-4,6-diphenyl-1,3,5-triazine 
• 2712-12-1 2-fluoroquinoxaline 
• 56595-09-6 4-fluoroquinazoline 
• 27484-67-9 2-fluoro-6-methylbenzothiazole 

Relevant academic research and scientific papers

The organocatalytic synthesis of perfluorophenylsulfides: Via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates

The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions. This journal is