16522-41-1

Basic information

• Product Name: 4-NITROPHENYL METHACRYLATE
• Synonyms: 4-NITROPHENYL METHACRYLATE;P-NITROPHENYL METHACRYLATE;Nsc301496
• CAS NO: 16522-41-1
• Molecular Formula: C₁₀H₉NO₄
• Molecular Weight: 207.18
• Product Categories: monomer
• Mol File: 16522-41-1.mol
• Article Data: 6

Chemical Properties

• Melting Point: 93-94 °C
• Boiling Point: 345.4°Cat760mmHg
• Flash Point: 162.3°C
• Appearance: /
• Density: 1.241g/cm³
• Vapor Pressure: 6.15E-05mmHg at 25°C
• Refractive Index: 1.547
• CAS DataBase Reference: 4-NITROPHENYL METHACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-NITROPHENYL METHACRYLATE(16522-41-1)
• EPA Substance Registry System: 4-NITROPHENYL METHACRYLATE(16522-41-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 16522-41-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H9NO4/c1-7(2)10(12)15-9-5-3-8(4-6-9)11(13)14/h3-6H,1H2,2H3

Upstream product

• 100-02-7 4-nitro-phenol 
• 920-46-7 Methacryloyl chloride 
• 463-49-0 1,2-propanediene 
• 201230-82-2 carbon monoxide 
• 814-68-6 acryloyl chloride 
• 79-41-4 poly(methacrylic acid) 

Downstream Products

• 893445-27-7 S-p-nitrophenyl 2-methylpropanethioate 
• 54667-28-6 S-phenyl 2-methylpropenethioate 

Relevant articles and documents

Control of the Alternating Sequence for N-Isopropylacrylamide (NIPAM) and Methacrylic Acid Units in a Copolymer by Cyclopolymerization and Transformation of the Cyclopendant Group

An alternating copolymer of methacrylic acid and N-isopropyl acrylamide (NIPAM) was synthesized by selective cyclopolymerization of a special divinyl monomer and transformation of repeating cyclo-units in the resultant cyclopolymer. Crucial to the breakthrough is the monomer design in view of two types of cleavable bonds (3° ester and activated ester) in the pendant group of the monomer and the lower reactivity ratio of the two double bonds (methacrylate and electron-poor acrylate) for the polymerizable groups. The thus-obtained cyclopolymer was transformed into the alternating copolymer by transformation of the activated ester into amide by isopropyl amine and cleavage of the 3° ester by trifluoroacetic acid. The resultant copolymer showed thermal and pH response in aqueous solution that was different from the 1:1 random copolymer as well as the homopolymers.

Isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters

A protocol for the isothiourea-catalysed transfer hydrogenation of α,β-unsaturated para-nitrophenyl esters using Hantzsch ester has been developed. Good to excellent yields are observed using α,β-unsaturated aryl esters bearing electron-withdrawing β-subs

Synthesis, characterization and reactivity ratios of co-polymers derived from 4-nitrophenyl methacrylate and butyl methacrylate

Poly (NPNA) has been synthesized from 4-nitrophenylmethacrylate (NPMA) in 2-butanone using BPO as a free radical initiator. Copolymers of NPMA and BMA [poly(NPMA-co-BMA)] have also likewise been obtained. The polymers have been characterized by IR, 1