1653-31-2

Basic information

• Product Name: 2-TRIDECANOL
• Synonyms: 2-Hydroxytridecane;tridecan-2-ol;METHYLUNDECYLCARBINOL;2-TRIDECANOL;2-TRIDECYL ALCOHOL;2-TRIDECANOL 98+%;Tridecane-2-ol
• CAS NO: 1653-31-2
• Molecular Formula: C₁₃H₂₈O
• Molecular Weight: 200.36
• EINECS: 216-723-1
• Mol File: 1653-31-2.mol
• Article Data: 29

Chemical Properties

• Melting Point: 29-30°C
• Boiling Point: 156-157°C 11mm
• Flash Point: 156-157°C/11mm
• Appearance: /
• Density: 0.83
• Vapor Pressure: 0.00219mmHg at 25°C
• Refractive Index: 1.4430
• PKA: 15.27±0.20(Predicted)
• BRN: 1720217
• CAS DataBase Reference: 2-TRIDECANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-TRIDECANOL(1653-31-2)
• EPA Substance Registry System: 2-TRIDECANOL(1653-31-2)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 1653-31-2(Hazardous Substances Data)

Usage

General Description

2-Tridecanol, also known as tridecyl alcohol, is a fatty alcohol with the chemical formula C13H28O. It is a waxy, white solid with a mild, floral odor. This chemical is primarily used as an emollient and emulsifier in the production of personal care products such as lotions, creams, and hair care products. It is also utilized as a surfactant in industrial applications and as a raw material for the synthesis of various other chemicals. Additionally, 2-Tridecanol can be found in some food products as a flavoring agent and is generally regarded as safe for consumption in small quantities. Overall, 2-Tridecanol has a range of uses due to its surfactant, emollient, and emulsifying properties, making it a versatile chemical in various industries.

InChI:InChI=1/C13H28O/c1-3-4-5-6-7-8-9-10-11-12-13(2)14/h13-14H,3-12H2,1-2H3/t13-/m0/s1

Upstream product

• 117286-10-9 undecylmagnesium bromide 
• 75-07-0 acetaldehyde 
• 113466-78-7 trans-2,3-Epoxy-1-tridecanol tosylate 
• 113466-78-7 (3-decyloxiran-2-yl)methyl 4-methylbenzenesulfonate 
• 534-22-5 2-methylfuran 
• 593-08-8 tridecan-2-one 
• 140145-80-8 trans-2,3-Epoxy-1-tridecanol tosylate 
• 67334-34-3 p-toluenesulfonic acid nonyl ester 
• 82275-99-8 5-(Toluene-4-sulfonyl)-pentan-2-one 
• 131701-87-6 (S)-(-)-5-p-toluenesulfonylpentane-2-ol 
• 111-83-1 1-bromo-octane 
• 74963-02-3 trans-2,3-Epoxy-1-tridecanol 
• 145107-44-4 Chloro-acetic acid 1-tert-butylsulfanylmethyl-undecyl ester 
• 146176-61-6 dodecyl 2,2,4,4-tetramethyl-1,3-oxazolidine-3-carboxylate 

Downstream Products

• 120876-13-3 (S)-(+)-1-methyldodecyl acetate 
• 140459-83-2 (R)-2-tridecanyl acetate 
• 59812-98-5 (R)-(-)-tridecan-2-ol 
• 1346758-16-4 1-methyldodecyl 3,5-dibromobenzoate 
• 41015-28-5 (+/-)-2-Tridecanyl acetate 
• 55193-07-2 Buttersaeure-2-tridecanester 
• 55193-94-7 Caprinsaeure-2-tridecylester 
• 593-08-8 tridecan-2-one 
• 61165-58-0 2-Tridecyl-p-dimethylamino-benzolsulfonat 

Relevant articles and documents

Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones

Three new dimeric bis-guanidinate zinc(II) alkyl, halide, and hydride complexes [LZnEt]2 (1), [LZnI]2 (2) and [LZnH]2 (3) were prepared. Compound 3 was successfully employed for the hydrosilylation and hydroboration of a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up to 5800 h-1, outperforming that of reported zinc hydride catalysts. Notably, both intra- and intermolecular chemoselective hydrosilylation and hydroboration reactions have been investigated.

Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane

The highly enantioselective cobalt-catalyzed hydroboration reaction of aryl ketones with HBpin was developed using iminopyridine oxazoline ligands. Halides, amines, ethers, sulfides, esters and amides are well tolerated under the mild reaction conditions, demonstrating its synthetic advantage. Substituted diaryl ketones could also be hydroborated with high enantioselectivity.

Tandem isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols using Rh/Ru dual-or ternary-catalyst systems

A one-pot three-step reaction, isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols, was accomplished by employing a Rh/Ru dual-catalyst system. By using a combination of Rh(acac)(CO)2/ bisphosphite and Shvo's catalyst, (Z)-2-tridecene was converted to 1-tetradecanol in 83% yield with high normal/iso selectivity (n/i = 12). The method was applicable to other internal alkenes, including functionalized alkenes, such as an alkenol and an alkenoate. Furthermore, addition of a third component, Ru3(CO)12, effectively improved the n/i ratio in the tandem isomerization/hydroformylation/hydrogenation of methyl oleate (from n/i = 1.9 to 4.4). Control experiments revealed that the isomerization was mediated by both Rh and Ru and that the coexistence of Rh and Ru was essential for hydrogenation of aldehyde under H2/CO.