1655-80-7Relevant academic research and scientific papers
THE SYNTHESIS AND TIN-119m MOESSBAUER SPECTRA OF SOME DIORGANOTIN DIHALIDE AND DIPSEUDOHALIDE COMPLEXES WITH NITROGEN AND OXYGEN-DONOR LIGANDS
Crowe, Alan J.,Smith, Peter J.
, p. 223 - 236 (2007/10/02)
The synthesis and 119mSn Moessbauer spectra of 114 complexes of the type R2SnX2, L2 (R = Me, Et, n-Pr, n-Bu, n-Oct, Ph, Bz; X = F, Cl, Br, I, NCS; L2 = 2 monodentate or 1 bidentate O- or N-donor ligand(s)), 74 of which are new, are reported.The majority of the complexes are isostructural, having an octahedral trans-R2SnX4 geometry about tin, whilst five of the diphenyltin complexes (R = Ph; X = Cl; L2 = AMP, Nphen; X = NCS; L2 = bipy, phen, TMphen) adopt a cis-R2SnX4 octahedral structure.A convenient method for the synthesis of a number of novel 1:1 diorganotin difluoride complexes using hot acetonitrile is reported and a structure for the unusual adduct, Ph2SnF2 * 0.5 phen, is proposed.
A NOVEL SYNTHETIC ROUTE TO DIORGANOTIN DICHLORIDES AND DIBROMIDES
Chandrasekaran, R. K.,Venkataraman, S.,Koola, Johnson D.
, p. C43 - C44 (2007/10/02)
Diorganotin dichlorides and dibromides can be prepared by a simple and convenient one-step process involving the reaction of Grignard reagent with (Acac)2SnX2 (Acac H = pentane-2,4-dione; X = Cl or Br).The yields of lower diorganotin dihalides are excellent while those of higher diorganotin dihalides are moderate.
Mechanisms of the rupture of the carbon-tin bond by halogens II. Free-radical substitution in solution
Boue, S,Gielen, M,Nasielski, J
, p. 461 - 479 (2008/10/08)
The experiments describes in this paper show that the light-induced bromodemetallation of tetraalkyltins in chlorobenzene is a free radical substitution on tin, followed by a propagation step: {A figure is presented}. The stabilisation of R? by hyperconjugation seems to be an important factor for the reaction, but there is evidence for the influence of the other three substituents of tin and of the nature of the attacking radical on the reaction mechanism. The relation between the strucutre and the reactivity of tetraalkyltins suggests that the carbon-tin bond is only slightly loosened in the transition state; this agrees with the great reactivity of the Br atom.
