16596-00-2

Basic information

• Product Name: N,N'-BIS-(3-CHLOROPHENYL)METHANIMIDAMIDE
• Synonyms: N,N'-BIS-(3-CHLOROPHENYL)METHANIMIDAMIDE;N,N-Bis(3-chlorophenyl)forMiMidaMide
• CAS NO: 16596-00-2
• Molecular Formula: C₁₃H₁₀Cl₂N₂
• Molecular Weight: 265.1379
• Mol File: 16596-00-2.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 388.7°Cat760mmHg
• Flash Point: 188.9°C
• Appearance: /
• Density: 1.24g/cm³
• CAS DataBase Reference: N,N'-BIS-(3-CHLOROPHENYL)METHANIMIDAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-BIS-(3-CHLOROPHENYL)METHANIMIDAMIDE(16596-00-2)
• EPA Substance Registry System: N,N'-BIS-(3-CHLOROPHENYL)METHANIMIDAMIDE(16596-00-2)

Safety Data

• Hazardous Substances Data: 16596-00-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 68, p. 1251, 1946 DOI: 10.1021/ja01211a033

Upstream product

• 68-12-2 N,N-dimethyl-formamide 
• 108-42-9 3-chloro-aniline 
• 4947-89-1 m-Cl-phenyl thiocarbamide 
• 94793-47-2 N-(3-Chloro-phenyl)-formamidine 
• 141-85-5 3-chloroaniline hydrochloride 
• 1219-84-7 1,3-bis(3-chlorophenyl)thiourea 
• 75-44-5 phosgene 
• 139-71-9 m-chloroformanilide 
• 122-51-0 orthoformic acid triethyl ester 
• 13208-31-6 N_.N'-Di-(m-chlor-phenyl)-harnstoff 
• 149-73-5 trimethyl orthoformate 
• 4947-89-1 1-(3-chlorophenyl)-2-thiourea 

Downstream Products

• 3412-99-5 2-(3-chlorophenylamino)methylenemalonic acid diethyl ester 
• 172226-68-5 Mo₂(m-ClC₆H₄NCHNC₆H₄-m-Cl)4 
• 253310-85-9 Re₂Cl₂((m-ClC₆H₄)NCHN(m-ClC₆H₄))4 
• 79138-39-9 4-[1-(3-Chloro-phenylamino)-meth-(Z)-ylidene]-2,5-dimethyl-2,4-dihydro-pyrazol-3-one 
• 61466-10-2 4-<(5-hydroxy-1,3-dimethyl-1H-pyrazol-4-yl)methylene>-2,5-dimethyl-2,4-dihydro-3H-pyrazol-3-one 
• 113430-64-1 2-(3-chloro-anilinomethylene)-N-(3-chloro-phenyl)-malonamic acid ethyl ester 
• 86-47-5 4-hydroxy-7-chloro-3-quinoline-carboxylic acid 

Relevant articles and documents

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Synthetic Applications of a New Magnetic Mesoporous Nanocomposite Catalyst Fe3O4@MCM-41@NH-SO3H

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Nanoporous TiO2 containing an ionic liquid bridge as an efficient and reusable catalyst for the synthesis of: N, N ′-diarylformamidines, benzoxazoles, benzothiazoles and benzimidazoles

In this work, a green and efficient procedure is reported for the preparation of N,N'-diarylformamidines, benzoxazoles, benzothiazoles, and benzimidazoles using nanoporous TiO2 containing an ionic liquid bridge. This reagent is prepared via the modification of nanoporous TiO2 with bis-3-(trimethoxysilylpropyl)-ammonium hydrogen sulfate (TiO2-[bip]-NH2+ HSO4-). The procedure gave the products in excellent yields in very short reaction times under solvent-free conditions. The reusability of the catalyst is the other important feature of the reported method.

Pushing back the limits of hydrosilylation: Unprecedented catalytic reduction of organic ureas to formamidines

Pushing back the limits: A novel catalytic transformation has been designed to prepare formamidine derivatives by reduction of substituted ureas with hydrosilanes. Simple iron catalysts based on commercially available iron salts and phosphine ligands prov