165967-25-9Relevant academic research and scientific papers
First synthesis of a digitalis saponin. Demonstration of the scope and limitations of a convergent scheme for branched oligosaccharide synthesis by the logic of glycal assembly
Randolph, John T.,Danishefsky, Samuel J.
, p. 5693 - 5700 (1995)
The synthesis of complex glycosides, with branching at C2, is demonstrated. The key element involves the use of a 1,2-oxirane donor. Upon glycosylation, a C2 hydroxyl is exposed to serve as the acceptor in the next glycosylation. Bra
