16601-19-7Relevant articles and documents
Selective monodesulfurization of organic trisulfides by bis(triphenylstannyl)chalcogenides
Li,Harpp
, p. 903 - 906 (1993)
Organic trisulfides undergo facile, selective monodesulfurization on treatment with bis(triphenylstannyl)chalcogenides. An intermolecular process is suggested.
Preparation method of asymmetric organic persulfide compound
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Paragraph 0210-0212, (2020/11/24)
The invention discloses a preparation method of an asymmetric organic persulfide compound, wherein the preparation method comprises the following step: under the catalysis of alkali, carrying out one-pot reaction on a compound represented by a formula (II), a compound represented by a formula (III) and sodium thiosulfate in a solvent to obtain the asymmetric organic persulfide compound representedby a formula (I). The preparation method disclosed by the invention is mild in reaction condition, simple to operate and high in yield; and the supervulcanization modification of natural product molecules such as quinolinone, coumarin, glucose and the like can be realized.
A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate
Soleiman-Beigi,Arzehgar
supporting information, p. 986 - 992 (2018/02/09)
An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O -Ethyl- S -aryl carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S -alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.