19717-02-3

Basic information

• Product Name: ethyl S-(4-methylphenyl) thiolcarbonate
• Synonyms: ethyl S-(4-methylphenyl) thiolcarbonate
• CAS NO: 19717-02-3
• Molecular Weight: 212.337
• Mol File: 19717-02-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: ethyl S-(4-methylphenyl) thiolcarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl S-(4-methylphenyl) thiolcarbonate(19717-02-3)
• EPA Substance Registry System: ethyl S-(4-methylphenyl) thiolcarbonate(19717-02-3)

Safety Data

• Hazardous Substances Data: 19717-02-3(Hazardous Substances Data)

Upstream product

• 140-89-6 potassium ethyl xanthogenate 
• 106-49-0 p-toluidine 
• 624-31-7 4-tolyl iodide 
• 106-38-7 para-bromotoluene 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 111-34-2 -butyl vinyl ether 
• 2028-84-4 p-methylbenzenediazonium chloride 

Downstream Products

• 22007-38-1 O-ethyl N-(4-methoxyphenyl)thiocarbamate 
• 55365-86-1 benzylthiocarbamic acid O-ethyl ester 
• 106-45-6 para-thiocresol 
• 3699-01-2 4-tolyl phenyl sulfide 
• 623-13-2 4-methylphenyl methylsulfide 
• 29627-34-7 4-(phenyldisulfanyl)toluene 
• 16601-19-7 1-(benzyl)-2-(4-methylphenyl)disulfide 
• 98-59-9 p-toluenesulfonyl chloride 
• 3111-89-5 O-ethyl-N-phenylthiocarbamate 
• 22001-51-0 O-ethyl N-(4-chlorophenyl)thiocarbamate 
• 5308-12-3 O-ethyl N-(4-methylphenyl)thiocarbamate 

Relevant articles and documents

A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate

An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O -Ethyl- S -aryl carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S -alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.

Synthesis of unsymmetrical sulfides using ethyl potassium xanthogenate and recyclable copper catalyst under ligand-free conditions

The synthesis of unsymmetrical sulfides has been achieved in good to excellent yields with inexpensive ethyl potassium xanthogenate via cross-coupling reaction using recyclable CuO nanoparticles under ligand-free conditions.The copper oxide nanoparticles can be recovered and reused up to five cycles without loss of activity.

Reactions of Aromatic Diazonium Salts with Butyl Vinyl Ether in the Presence of Potassium O-Alkyl Dithiocarbonates

Arenediazonium tetrafluoroborates, sulfates, and nitrates react with butyl vinyl ether in aqueous acetone in the presence of potassium O-alkyl dithiocarbonates to yield O-alkyl S-(2-aryl-1-butoxyethyl) dithiocarbonates (Alk = Et, Bu, t-Bu). The reaction is accompanied by formation of O-alkyl S-aryl dithiocarbonates, which are the main products of the reaction of arenediazonium salts with potassium O-alkyl dithiocarbonates in the absence of unsaturated compound.