166411-39-8

Basic information

• Product Name: 5-O-benzoyl-1,2-O-isopropylidene-7α-L-xylofuranose
• Synonyms: 5-O-benzoyl-1,2-O-isopropylidene-7α-L-xylofuranose
• CAS NO: 166411-39-8
• Molecular Weight: 294.304
• Mol File: 166411-39-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 5-O-benzoyl-1,2-O-isopropylidene-7α-L-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-O-benzoyl-1,2-O-isopropylidene-7α-L-xylofuranose(166411-39-8)
• EPA Substance Registry System: 5-O-benzoyl-1,2-O-isopropylidene-7α-L-xylofuranose(166411-39-8)

Safety Data

• Hazardous Substances Data: 166411-39-8(Hazardous Substances Data)

Upstream product

• 114861-22-2 1,2-O-isopropylidene-α-L-xylofuranose 
• 1333476-27-9 C₁₉H₂₂O₈ 
• 1333476-25-7 5-O-allyloxycarbonyl-1,2-O-isopropylidene-α-L-xylofuranose 
• 41546-31-0 L-xylose 
• 131156-47-3 (3aS,3bR,7aS,8aS)-2,2,5,5-tetramethyltetrahydro-3aH-[1,3]dioxolo[4',5':4,5]furo[3,2-d][1,3]dioxane 
• 609-06-3 L-xylose 
• 100-44-7 benzyl chloride 
• 98-88-4 benzoyl chloride 

Downstream Products

• 1333476-29-1 diethyl (5S)-(3-O-benzyl-1,2-O-isopropylidene-α-L-xylofuranos-5-C-yl)phoshonate 
• 391201-57-3 [(3aS,5S,6R,6aS)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methanol 
• 145772-63-0 (3aS,5R,6R,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole-5-carbaldehyde 
• 169823-50-1 Benzoic acid (2R,4S,5S)-4-acetoxy-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl ester 
• 166411-41-2 5-O-benzoyl-1,2-O-isopropylidene-p-toluenesulfonylhydrazone-α-L-erythro-pentofurano-3-ulose 
• 171721-11-2 5-O-benzoyl-1,2-O-isopropylidene-α-L-ribofuranose 
• 171720-99-3 1,3,5-tri-O-benzoyl-2-O-(2-imidazolylsulfonyl)-α-L-ribofuranose 
• 171721-05-4 N⁴-benzoyl-1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-iodocytosine 
• 178688-01-2 1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-[2-(trimethylsilyl)acetylenyl]uracil 
• 178687-86-0 N⁴-benzoyl-1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)cytosine 
• 178687-93-9 1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-(trifluoromethyl)uracil 
• 171721-06-5 1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-iodouracil 
• 171721-04-3 1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-ethyluracil 
• 178687-91-7 1-(3,5-di-O-benzoyl-2-deoxy-2-fluoro-β-L-arabinofuranosyl)-5-bromouracil 

Relevant articles and documents

1,2-Di-O-acetyl-5-O-benzoyl-3-deoxy-L-erythro-pentofuranose, a convenient precursor for the stereospecific synthesis of nucleoside analogues with the unnatural β-L-configuration

The title compound 1,2-di-O-acetyl-5-O-benzoyl-3-deoxy-L-erythro- pentofuranose (5), a useful precursor for the stereospecific synthesis of β- L-nucleoside analogues as potential antiviral agents, has been synthesised by a multi-step reaction sequence from L-xylose with a 38% overall yield. The preparation involved conversion of L-xylose to 1,2-O-isopropylidene-α-L- xylofuranose which, upon selective 5-O-benzoylation and subsequent radical deoxygenation, provided the protected 3-deoxy sugar derivative. Finally, cleavage of the acetonide group gave the resulting 5-O-benzoyl-3-deoxy-L- erythro-pentose which was acetylated to afford crystalline α,β-5. (C) 2000 Elsevier Science Ltd.

Tetrofuranose nucleoside phosphonic acids: Synthesis and properties

New isoelectronic, non-isosteric phosphonate analogues of nucleoside 5'-phosphates featuring the phosphorus moiety directly attached on the sugar ring in the C4' position are described. The analogues were synthesised by a nucleosidation reaction from tetr

Enantioselective total syntheses of slagenins A-C and their antipodes

Full details of the total syntheses of slagenins A-C (1a-c) and their antipodes (2a-c), novel bromopyrrole alkaloids with a unique tetrahydrofuro[2,3-d]imidazolidin-2-one moiety, are described in which their absolute stereochemistry was established. The key step in the syntheses involves the efficient condensation of dihydrofuran-3-one or glyoxal with urea to construct the slagenin bicycle core.