16654-47-0Relevant academic research and scientific papers
Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates
Chauvier, Clément,Godou, Timothé,Cantat, Thibault
supporting information, p. 11697 - 11700 (2017/11/03)
The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.
Silica sulfate, an efficient catalyst for the trimethylsilylation of alcohols
Jin, Tong-Shou,Tian, Ruo-Fei,Liu, Li-Bin,Zhao, Ying,Li, Tong-Shuang
, p. 1823 - 1828 (2007/10/03)
An easy method for the preparation of trimethylsilyl ethers from alcohols and 1,1,1,3,3,3-hexamethyl-disilazane (HMDS) using silica sulfate as a catalyst under mild conditions in excellent yields is described. Copyright Taylor & Francis Group, LLC.
Phosphomolybdic acid, an efficient catalyst for the trimethylsilylation of alcohols
Jin, Tong-Shou,Li, Yan-Wei,Sun, Guang,Li, Tong-Shuang
, p. 456 - 458 (2007/10/03)
An easy method for the preparation of trimethylsilyl ethers of alcohols with 1,1,1,3,3,3-hexamethyl- disilazane (HMDS) catalysed by phosphomolybdic acid (PMA) under mild conditions has been carried out in excellent yields.
Montmorillonite clay catalysis XI1: Protection and deprotection of hydroxyl group by formation and cleavage of trimethylsilyl ethers catalysed by catalysed by montmorillonite K-10
Zhang, Zhan-Hui,Li, Tong-Shuang,Yang, Feng,Fu, Cheng-Guang
, p. 3105 - 3114 (2007/10/03)
An easy preparation of trimethylsilyl ethers of alcohols and phenols with 1,1,1,3,3,3-hexamethyldisilazane(HMDS) catalysed by montmorillonite K- 10 at room temperature has been carried out in excellent yields. Desilyation of trimeylsilyl ethers is catalysed by K-10 in methanol at ambient temperature in high yields.
