16654-47-0

Basic information

• Product Name: (2-Phenoxyethoxy)trimethylsilane
• Synonyms: (2-Phenoxyethoxy)trimethylsilane
• CAS NO: 16654-47-0
• Molecular Formula: C₁₁H₁₈O₂Si
• Molecular Weight: 210.34
• Mol File: 16654-47-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2-Phenoxyethoxy)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Phenoxyethoxy)trimethylsilane(16654-47-0)
• EPA Substance Registry System: (2-Phenoxyethoxy)trimethylsilane(16654-47-0)

Safety Data

• Hazardous Substances Data: 16654-47-0(Hazardous Substances Data)

Upstream product

• 122-99-6 2-Phenoxyethanol 
• 18243-21-5 trimethylsilyl formate 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 122-99-6 2-Phenoxyethanol 

Relevant articles and documents

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.

Phosphomolybdic acid, an efficient catalyst for the trimethylsilylation of alcohols

An easy method for the preparation of trimethylsilyl ethers of alcohols with 1,1,1,3,3,3-hexamethyl- disilazane (HMDS) catalysed by phosphomolybdic acid (PMA) under mild conditions has been carried out in excellent yields.