18243-21-5Relevant academic research and scientific papers
Kinetics and Products of the Gas-phase Reactions of (CH3)4Si, (CH3)3SiCH2OH, (CH3)3SiOSi(CH3)3 and (CD3)3SiOSi(CD3)3 with Cl Atoms and OH Radicals
Atkinson, Roger,Tuazon, Ernesto C.,Kwok, Eric S. C.,Arey, Janet,Aschmann, Sara M.,Bridier, Isabelle
, p. 3033 - 3040 (1995)
Direct air-sampling atmospheric-pressure ionisation tandem mass spectrometry and FTIR spectroscopy were used to analyse the products of the OH radical- and Cl atom-imitiated reactions of hexamethyldisiloxane, hexamethyldisiloxane, tetramethylsilane and trimethylsilylmethanol at room temperature and atmospheric pressure.The data obtained indicate the initial formation of (CH3)3SiOSi(CH3)2OCHO and (CD3)3SiOSi(CD3)2OCDO from hexamethyldisiloxane and hexamethyldisiloxane, respectively, and (CH3)3SiOCHO from both tetramethylsilane and trimethylsilylmethanol.
Trimethylsilyl group migration in the Criegee intermediate of gas-phase ozonolysis of trimethylsilylethenes
Fajgar, Radek,Pola, Josef
, p. 2435 - 2438 (2007/10/03)
GC, GC/MIS and GC/FTIR analyses of the final products of ozonolysis of trimethylsilylethene and trans-1,3-bis(trimethylsilyl)ethene reveal that the ester channel of decomposition of the Criegee intermediate takes place exclusively via migration of Me
Reagents and synthetic methods. 31. Silylations with N-trimethylsilyl-2-oxazolidinone (TMSO)
Aizpurua, Jesus M.,Palomo, Claudio,Palomo, Antonio L.
, p. 336 - 340 (2007/10/02)
Silylation of ketones, alcohols, mercaptans, and carboxylic acids with N-trimethylsilyl-2-oxazolidinone (TMSO) and triflic acid as catalyst has been described from synthetic and mechanistic points of view.
