167072-96-0Relevant academic research and scientific papers
Studies in the directed cyclopropanation of α-allenic alcohols
Lautens, Mark,Delanghe, Patrick H. M.
, p. 8526 - 8535 (2007/10/02)
A highly regioselective cyclopropanation of α-allenic alcohols using samarium/dihalomethane provides a variety of methylene- and alkylidenecyclopropane carbinols in good yield. The nearby hydroxyl moiety and the samarium reagent are essential for this uni
Regioselective Cyclopropanation of α-Allenic Alcohols. An Efficient Route to Alkylidenecyclopropanes
Lautens, Mark,Delanghe, Patrick H. M.
, p. 5037 - 5039 (2007/10/02)
Highly substituted alkylidenecyclopropanes are now easily accessible via a regioselective cyclopropanation of α-allenic alcohols using samarium/CH2I2.Dienols provide vinylcyclopropylcarbinols upon methylenation.
