109907-84-8Relevant articles and documents
A General CuCl2-Promoted Alkene Aminochlorination Reaction
Li, Shu-Qi,Xiong, Peng,Zhu, Lin,Qian, Xiang-Yang,Xu, Hai-Chao
supporting information, p. 3449 - 3455 (2016/07/23)
A CuCl2-promoted alkene aminochlorination reaction has been developed. A variety of anilides that contain a mono-, di-, or trisubstituted alkenyl moiety readily participated in this reaction to afford structurally diverse vicinal chloroamines. Studies suggest that the process proceeds by a radical-type mechanism and that CuCl2serves as both the oxidant to generate the amidyl radical as well as the chloride source.
CuI-catalyzed synthesis of functionalized terminal allenes from 1-alkynes
Luo, Hongwen,Ma, Shengming
, p. 3041 - 3048 (2013/06/27)
Relative to our original protocol that uses CuI (0.5 equiv.), paraformaldehyde (2.5 equiv.), and dicyclohexylamine (1.8 equiv.), a facile and efficient protocol for the gram-scale synthesis of functionalized terminal allenes by using CuI (7.5-10 mol-%), p
Chiral Bronsted acid catalyzed enantioselective allenylation of aldehydes
Reddy, Leleti Rajender
, p. 9189 - 9191 (2012/09/22)
A versatile and highly enantioselective chiral Bronsted acid-catalyzed allenylation of aldehydes with propargyl borolane is reported. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, heteroaryl, α,β-unsaturated, and aliphatic aldehydes.