16737-31-8

Basic information

• Product Name: 2-methyl-1-phenylpropan-2-yl benzoate
• Synonyms: 2-methyl-1-phenylpropan-2-yl benzoate
• CAS NO: 16737-31-8
• Molecular Weight: 254.329
• Mol File: 16737-31-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-methyl-1-phenylpropan-2-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-1-phenylpropan-2-yl benzoate(16737-31-8)
• EPA Substance Registry System: 2-methyl-1-phenylpropan-2-yl benzoate(16737-31-8)

Safety Data

• Hazardous Substances Data: 16737-31-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 100-86-7 2-Methyl-1-phenyl-2-propanol 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 65-85-0 benzoic acid 
• 612058-41-0 (1,1,-dimethyl-2-phenylethoxy)di(phenyl)phosphine 
• 93-97-0 benzoic acid anhydride 
• 38425-59-1 (1-ethoxy)vinyl benzoate 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

A novel nickel-catalyzed synthesis of thioesters, esters and amides from aryl iodides in the presence of chromium hexacarbonyl

This study describes our findings on a novel and cheap NiCl2 catalytic system under ligand-free conditions for the efficient thiocarbonylation, alkoxycarbonylation and amidocarbonylation reactions of aryl iodides in the presence of Cr(CO)6 as the solid source of carbon monoxide under air. A variety of aryl iodides tolerated the reaction conditions and structurally different thiols, alcohols and amines were used efficiently. The corresponding thioesters, esters and amides were obtained in good to excellent yield at atmospheric pressure under mild reaction conditions.

Dual activation in the esterification of hindered alcohols with anhydrides using MgBr2 and a tertiary amine

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