167693-07-4

Basic information

• Product Name: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-phenylbutyl)-
• Synonyms: 1,3,2-Dioxaborolane,4,4,5,5-tetramethyl-2-(4-phenylbutyl);D-1413;2-(4-phenylbutyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butane
• CAS NO: 167693-07-4
• Molecular Formula: C16H25BO2
• Molecular Weight: 260.184
• Mol File: 167693-07-4.mol
• Article Data: 43

Chemical Properties

• CAS DataBase Reference: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-phenylbutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-phenylbutyl)-(167693-07-4)
• EPA Substance Registry System: 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-phenylbutyl)-(167693-07-4)

Safety Data

• Hazardous Substances Data: 167693-07-4(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 768-56-9 4-Phenylbut-1-ene 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 16520-62-0 4-Phenyl-1-butyne 
• 73183-34-3 bis(pinacol)diborane 
• 13633-25-5 1-Bromo-4-phenylbutane 
• 165904-22-3 4,4,5,5-tetramethyl-2-phenethyl-1,3,2-dioxaborolane 
• 74-97-5 chlorobromomethane 
• 329685-40-7 4,4,5,5-tetramethyl-2-(3-phenylpropyl)-[1,3,2]dioxaborolane 
• 13826-27-2 2,2'-bis(1,3,2-benzodioxaborole) 
• 1570511-19-1 2,2'-(4-phenylbutane-1,1-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) 
• 2270-20-4 5-Phenylpentanoic acid 

Downstream Products

• 36884-28-3 5-phenyl-1-pentanal 
• 36329-86-9 (4-phenylbutyl)boronic acid 
• 10521-91-2 5-phenylpentan-1-ol 
• 20620-59-1 5-phenyl-n-valeric acid methyl ester 
• 3360-41-6 4-phenyl-butan-1-ol 

Relevant articles and documents

Synthesis of DBpin using Earth-abundant metal catalysis

The synthesis of DBpin was achieved using (EtBIP)CoCl2 or (tBuPNN)FeCl2 as pre-catalysts activated with NaOtBu. (EtBIP)CoCl2 was used as a pre-catalyst for the hydrogen isotope exchange of HBpin with D2, and (tBuPNN)FeCl2 for deuterogenolysis of B2pin2. The one-pot, tandem hydrogenolysis-hydroboration/deuterogenolysis-deuteroboration reaction of terminal alkenes could be catalysed by (tBuPNN)FeCl2 to give alkyl boronic esters.

Copper-Photocatalyzed Hydroboration of Alkynes and Alkenes

The photocatalytic hydroboration of alkenes and alkynes is reported. The use of newly-designed copper photocatalysts with B2Pin2 permits the formation a boryl radical, which is used for hydroboration of a large panel of alkenes and a

Photoinduced NaI-Promoted Radical Borylation of Alkyl Halides and Pseudohalides

A method for photoinduced NaI-promoted radical borylation of aliphatic halides and pseudohalides with bis(catecholato)diboron (B2cat2) as the boron source is introduced. The borylation reaction is operationally simple and shows high