167700-64-3

Upstream product

• 99946-79-9 1-(methylthio)-1-butyl p-tolyl sulfate 
• 99946-82-4 1-chloro-1(methylthio)-1-butyl p-tolyl sulfone 

Downstream Products

• 167700-65-4 3-Bromo-1-(methylthio)-1-(p-tolylsulfonyl)-1-butene 
• 197391-48-3 1-((E)-3-Bromo-1-methylsulfanyl-but-1-ene-1-sulfonyl)-4-methyl-benzene 
• 167700-85-8 2-[Methylsulfanyl-(toluene-4-sulfonyl)-methyl]-butane-1,3-diol 
• 167700-67-6 (Z)-4-Methylsulfanyl-4-(toluene-4-sulfonyl)-but-3-en-2-ol 
• 167700-66-5 (E)-4-Methylsulfanyl-4-(toluene-4-sulfonyl)-but-3-en-2-ol 
• 99947-03-2 (E)-4-(methylthio)-5-phenyl-2-penten-2-yl p-tolyl sulfone 
• 99947-04-3 (Z)-4-(methylthio)-5-phenyl-2-penten-2-yl p-tolyl sulfone 
• 99947-01-0 (E)-4-(methylthio)-3-penten-2-yl p-tolyl sulfone 
• 99947-02-1 (Z)-4-(methylthio)-3-penten-2-yl p-tolyl sulfone 
• 99947-22-5 1-Methyl-4-((E)-4-methyl-2-methylsulfanyl-1-phenyl-oct-2-ene-4-sulfonyl)-benzene 
• 219533-76-3 2-[Methylsulfanyl-(toluene-4-sulfonyl)-methyl]-1-phenyl-butan-1-one 
• 197391-18-7 Acetic acid (E)-1-methyl-3-methylsulfanyl-3-(toluene-4-sulfonyl)-allyl ester 

Relevant academic research and scientific papers

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)