99946-79-9

Upstream product

• 59662-65-6 methylthiomethyl p-tolyl sulfone 

Downstream Products

• 99947-03-2 (E)-4-(methylthio)-5-phenyl-2-penten-2-yl p-tolyl sulfone 
• 99947-04-3 (Z)-4-(methylthio)-5-phenyl-2-penten-2-yl p-tolyl sulfone 
• 99947-01-0 (E)-4-(methylthio)-3-penten-2-yl p-tolyl sulfone 
• 99947-02-1 (Z)-4-(methylthio)-3-penten-2-yl p-tolyl sulfone 
• 99946-85-7 (E)-1-(methylthio)-1-buten-1-yl p-tolyl sulfone 
• 167700-64-3 (Z)-1-(methylthio)-1-buten-1-yl p-tolyl sulfone 
• 99947-22-5 1-Methyl-4-((E)-4-methyl-2-methylsulfanyl-1-phenyl-oct-2-ene-4-sulfonyl)-benzene 
• 99946-93-7 1-Methyl-4-((Z)-2-methylsulfanyl-1-phenyl-pent-3-ene-2-sulfonyl)-benzene 
• 99946-91-5 1-Methyl-4-((Z)-2-methylsulfanyl-pent-3-ene-2-sulfonyl)-benzene 
• 99946-82-4 1-chloro-1(methylthio)-1-butyl p-tolyl sulfone 

Relevant academic research and scientific papers

Electrophilic behavior of lithiated 1-alkoxyalkyl and 1-alkylthioalkyl sulfones. Regioselective synthesis of enol ethers and vinyl sulfides

The readily available 1-alkoxyalkyl and 1-alkylthioalkyl sulfones display electrophilic behavior when lithiated.For example, both react regioselectively with lithiated alkyl sulfones to give enol ethers and vinyl sulfides, respectively.A series of methyl and tert-butyl enol ethers and vinyl sulfides have been prepared. - Keywords: sulfones / alkoxyalkyl sulfones / carbenoids / enol ethers / heterosubstituted carbanions / alkylthioalkyl sulfones / vinyl sulfides

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)