99947-03-2

Upstream product

• 99946-79-9 1-(methylthio)-1-butyl p-tolyl sulfate 
• 99946-82-4 1-chloro-1(methylthio)-1-butyl p-tolyl sulfone 
• 167700-64-3 (Z)-1-(methylthio)-1-buten-1-yl p-tolyl sulfone 
• 59662-65-6 methylthiomethyl p-tolyl sulfone 
• 99946-93-7 1-Methyl-4-((Z)-2-methylsulfanyl-1-phenyl-pent-3-ene-2-sulfonyl)-benzene 

Relevant academic research and scientific papers

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)