168126-70-3Relevant academic research and scientific papers
Direct, enantioselective iridium-catalyzed allylic amination of racemic allylic alcohols
Lafrance, Marc,Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 3470 - 3473 (2012/06/01)
The direct route: Iridium-catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio- and enantioselective (see scheme; coe=cyclooctene). Copyright
Asymmetric synthesis of α-amino aldehydes from sulfinimine (N-sulfinyl imine)-derived α-amino 1,3-dithianes. Formal synthesis of (-)-2,3-trans-3,4-cis-dihydroxyproline
Davis, Franklin A.,Ramachandar, Tokala,Chai, Jing,Skucas, Eduardas
, p. 2743 - 2746 (2007/10/03)
Hydrolysis of sulfinimine-derived N-sulfinyl α-amino 1,3-dithianes with aqueous 1,3-dibromo-5,5-dimethylhydantoin affords the corresponding N-tosyl α-amino aldehydes in good yield and high enantiomeric purity. These aldehydes can be reduced to amino alcoh
