16823-62-4

Basic information

• Product Name: (butylsulfonyl)benzene
• CAS NO: 16823-62-4
• Molecular Formula: C₁₀H₁₄O₂S
• Molecular Weight: 198.282
• Mol File: 16823-62-4.mol
• Article Data: 48

Chemical Properties

• Boiling Point: 337.8°C at 760 mmHg
• Flash Point: 186.9°C
• Density: 1.097g/cm³
• Vapor Pressure: 0.0002mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: (butylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (butylsulfonyl)benzene(16823-62-4)
• EPA Substance Registry System: (butylsulfonyl)benzene(16823-62-4)

Safety Data

• Hazardous Substances Data: 16823-62-4(Hazardous Substances Data)

Usage

General Description

"(Butylsulfonyl)benzene" is a chemical compound with the molecular formula C10H14S. It is an organic compound that consists of a benzene ring with a butylsulfonyl group attached. (butylsulfonyl)benzene is known for its use as a reagent in organic synthesis and as a building block for the production of various pharmaceuticals and agrochemicals. It is also used as a solvent and in the manufacturing of dyes and pigments. (Butylsulfonyl)benzene is a colorless to pale yellow liquid with a strong, aromatic odor, and it is considered to be a flammable substance. It is important to handle and store this chemical with caution due to its potential hazards.

Upstream product

• 109-65-9 1-bromo-butane 
• 873-55-2 sodium benzenesulfonate 
• 3112-85-4 methylphenylsulfonate 
• 106-94-5 propyl bromide 
• 5535-48-8 PVS 
• 1126-80-3 (n-butylthio)benzene 
• 109-72-8 n-butyllithium 
• 426-58-4 (trifluoromethylsulfonyl)benzene 
• 109-69-3 n-Butyl chloride 
• 603-33-8 triphenylbismuthane 
• 542-69-8 1-iodo-butane 
• 591-50-4 iodobenzene 
• 79458-33-6 1-butanesulfonyl azide 
• 71-43-2 benzene 

Downstream Products

• 67886-64-0 Methyl 3-methyl-4-phenylsulfonylheptanoat 
• 107-92-6 butyric acid 
• 1361023-10-0 [(4RS,7S)-7,11-dimethyldodec-10-en-4-yl](phenyl)sulfone 
• 1361023-03-1 (4RS,7R)-7,11-dimethyldodec-10-en-4-yl(phenyl)sulfone 
• 1361023-11-1 (4S,7RS)-4-methyl-7-phenylsulfonyldecan-1-ol 
• 1361023-04-2 (4R,7RS)-4-methyl-7-phenylsulfonyldecan-1-ol 
• 67886-43-5 Phosphoric acid (E)-2-benzenesulfonyl-1-cyclohexyl-pent-1-enyl ester diethyl ester 
• 67886-44-6 Phosphoric acid (Z)-2-benzenesulfonyl-1-cyclohexyl-pent-1-enyl ester diethyl ester 
• 67886-47-9 Phosphoric acid (Z)-2-benzenesulfonyl-1-phenyl-pent-1-enyl ester diethyl ester 
• 67886-61-7 1-Cyclohexyl-2-phenylsulfonyl-1-penten 
• 67886-53-7 pent-1-ynylcyclohexane 
• 4250-81-1 1-phenyl-1-pentyne 
• 776247-30-4 3-Aminophenyl-butylsulfon 
• 421598-88-1 (4S)-tert-butyl-2-((2R,3S)-2-phenyl-3-phenylsulfonylhexyl)-oxazoline 

Relevant articles and documents

Organic reactions in ionic liquids: A new method for the synthesis of alkyl aryl sulfones by alkylation of sodium arenesulfinates with unactivated alkyl chlorides

A new method is reported for the synthesis of alkyl aryl sulfones by alkylation of sodium arenesulfinates with unactivated alkyl chlorides using ionic liquid based on 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF 4) mixed with water (2:1) as reaction media. The ionic liquid can be reused and the procedure gives the sulfones in moderate yields.

Ortho-bis (alkylsulphonyl) benzenes: The fate of their electrochemically formed anion radical: SN2 vs cleavage reaction

Title compounds are electrochemically reduced into anion radicals of rather long lifetime. Surprisingly decomposition of such intermediates does not correspond as expected to a pure sulphur-carbon bond cleavage but mainly to a nucleophilic substitution toward the substrate. Nevertheless, cleavage reactions are observed in the case of methyl compounds.

Highly efficient and selective aqueous aerobic oxidation of sulfides to sulfoxides or sulfones catalyzed by tungstate-functionalized nanomaterial

A Br?nsted acidic ionic solid comrising tungstate-functionaized polyorganosiloxane framework (PMO-IL-WO42?) efficiently catalysed aerobic oxidation of sulfides in aqueous medium. The catalyst can selectively produce sulfoxides or sulfones by running the reaction at room temperature or 50 °C, respectively. Because of the ionic liquid-based charged surface containing hydrophobic organic functional groups and hydrophilic sulfonic acid group, the synergestic hydrophobic/hydrophilic and redox effect of PMO-IL-WO42- as water-friendly interfacial nanocatalyst simplifies and enhances the activity and selectivity toward the target sulfoxides or sulfones in water. Moreover, the PMO-IL-WO42- nanocatalyst exhibited outstanding stability and activity and can be recycled eight reaction runs without any significant activity and selectivity loss.

Multicomponent Synthesis of Sulfones and Sulfides from Triarylbismuthines and Sodium Metabisulfite in Deep Eutectic Solvents

This study describes a novel and catalyst-free methodology for the multicomponent synthesis of a broad range of sulfones, disulfides, and sulfides from non-toxic triarylbismuthines (Ar3Bi) and sodium metabisulfite (Na2S2O5) in deep eutectic solvents (DESs). The fine tuning of the DESs properties allowed the solubility of all reagents, enhancing their reactivity, as well as, the recyclability of the reaction medium for at least 5 consecutive cycles. Thus, this versatile strategy uses non-toxic reagents without the need of metal catalysts in a sustainable solvent, being an interesting alternative to traditional hazardous protocols.