1683-20-1Relevant articles and documents
Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant
Iturmendi, Amaia,Iglesias, Manuel,Munárriz, Julen,Polo, Victor,Pérez-Torrente, Jesús J.,Oro, Luis A.
supporting information, p. 404 - 407 (2017/01/03)
The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.