16841-48-8

Basic information

• Product Name: diallyl sulfone
• Synonyms: 1-Propene,3,3'-sulfonylbis- (9CI); Allyl sulfone (6CI,7CI,8CI); Bis(allyl) sulfone;Diallyl sulfone; NSC 10979
• CAS NO: 16841-48-8
• Molecular Formula: C₆H₁₀O₂S
• Molecular Weight: 146.21
• Mol File: 16841-48-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 128°C
• Flash Point: 125°C
• Appearance: /
• Density: 1.1213
• Vapor Pressure: 0.0192mmHg at 25°C
• Refractive Index: 1.4893 (estimate)
• CAS DataBase Reference: diallyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: diallyl sulfone(16841-48-8)
• EPA Substance Registry System: diallyl sulfone(16841-48-8)

Safety Data

• Hazardous Substances Data: 16841-48-8(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron, 52, p. 5773, 1996 DOI: 10.1016/0040-4020(96)00202-5

InChI:InChI=1/C6H10O2S/c1-3-5-9(7,8)6-4-2/h3-4H,1-2,5-6H2

Upstream product

• 624-31-7 4-tolyl iodide 
• 30535-30-9 allyl(methoxy)dimethylsilane 
• 2551-83-9 allyltrimethoxysilane 

Downstream Products

• 598-03-8 propyl sulfone 
• 6633-86-9 2,6-dimethyl-[1,4]oxathiane-4,4-dioxide 
• 129110-97-0 2-iodo-1,3-bis(p-tolylsulphonyl)propane 
• 129110-96-9 Bis(2-iodo-3-p-tolylsulphonylpropyl)sulphone 
• 129110-94-7 3-iodomethyl-4-(p-tolylsulphonylmethyl)tetrahydrothiofen-di-S-oxide (trans) 
• 129110-94-7 3-iodomethyl-4-(p-tolylsulphonylmethyl)tetrahydrothiofen-di-S-oxide (cis) 
• 3112-87-6 1-methyl-4-(prop-2-ene-1-sulfonyl)benzene 
• 129110-92-5 3-bromomethyl-4-(p-tolylsulphonylmethyl)tetrahydrothiofen-di-S-oxide (trans) 
• 129110-92-5 3-bromomethyl-4-(p-tolylsulphonylmethyl)tetrahydrothiofen-di-S-oxide (cis) 
• 77-79-2 3-Sulfolene 
• 200072-28-2 [PdBr(η(1)-η(2)-pentafluorophenyl-CH2CH2CHSO2CH2CH=CH2)]2 
• 200072-24-8 [PdBr(η(1)-η(2)-pentafluorophenyl-CH2CHCH2SO2CH2CH=CH2)]2 
• 114600-97-4 1-Benzyl-2,6-dimethyl-4,1-thiazane 4,4-dioxide 
• 114601-01-3 Di<2-(cyclohexylamino)propyl> sulfone 

Relevant articles and documents

SO2 conversion to sulfones: Development and mechanistic insights of a sulfonylative Hiyama cross-coupling

A Pd-catalyzed Hiyama cross-coupling reaction using SO2 is described. The use of silicon-based nucleophiles leads to the formation of allyl sulfones under mild conditions with a broad functional group tolerance. Control experiments coupled with DFT calculations shed light on the key steps of the reaction mechanism, revealing the crucial role of a transient sulfinate anion.