30535-30-9Relevant academic research and scientific papers
Far-UV laser flash photolysis in solution. A time-resolved spectroscopic study of the chemistry of 1,1-dimethyl-1,3-(1-sila)- butadiene
Kerst, Corinna,Byloos, Martin,Leigh, William J.
, p. 975 - 982 (2007/10/03)
Laser flash photolysis (193 nm) of 1,1-dimethyl-(1-sila)cyclobut-2-ene in hexane solution leads to the formation of a transient species (τ ～ 1.5 μs at 23°C) assigned to 1,1-dimethyl-1,3-(1-sila)butadiene on the basis of its UV absorption spectrum (λm
THE BEHAVIOR OF ALKOXIDES WITH ALLYL(CHLOROMETHYL)DIMETHYLSILANES AND (CHLOROMETHYL)DIMETHYLVINYLSILANE; THE ABILITIES OF ALLYL AND VINYL GROUPS TO MIGRATE FROM PENTACOORDINATE SILICON
Sans, E. A.,Shechter, H.
, p. 1119 - 1122 (2007/10/02)
Sodium methoxide in tetrahydrofuran attacks silicon in allyl(chloromethyl)-dimethylsilane and in (chloromethyl)dimethylvinylsilane with displacement of chloride and 1,2-migration of the allyl and the vinyl groups to give 1-(3-butenyl)methoxydimethylsilane and allylmethoxydimethylsilane.
