168848-36-0

Basic information

• Product Name: methyl 3-deoxy-4,6-O-phenylmethenyl-α-D-altropyranosido-3-diphenylphosphine
• Synonyms: methyl 3-deoxy-4,6-O-phenylmethenyl-α-D-altropyranosido-3-diphenylphosphine
• CAS NO: 168848-36-0
• Molecular Weight: 450.471
• Mol File: 168848-36-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 3-deoxy-4,6-O-phenylmethenyl-α-D-altropyranosido-3-diphenylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-deoxy-4,6-O-phenylmethenyl-α-D-altropyranosido-3-diphenylphosphine(168848-36-0)
• EPA Substance Registry System: methyl 3-deoxy-4,6-O-phenylmethenyl-α-D-altropyranosido-3-diphenylphosphine(168848-36-0)

Safety Data

• Hazardous Substances Data: 168848-36-0(Hazardous Substances Data)

Upstream product

• 65567-06-8 lithium diphenylphosphide 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 2880-96-8 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside 
• 829-85-6 diphenylphosphane 

Downstream Products

• 1609168-27-5 C₂₇H₂₉O₅P 

Relevant articles and documents

An Effective Method to Incorporate Phosphorus Atoms into Secondary Carbons Pyranosides

Two new chiral phosphines, methyl 3-deoxy-3-(diphenylphosphino)-4,6-O-benzylidene-α-D-altropyranoside (3) and methyl 2-deoxy-2-(diphenylphosphino)-4,6-O-benzylidene-α-D-altropyranoside (4), have been prepared in high yields from D-glucose via regioselective and stereospecific ring-opening of epoxides 3 and 4 have been characterized by 1H, 13C, 31P NMR and MS spectra.Crystal structure of 3 has been determined by the single-crystal X-ray diffraction analysis.

Tunable ligands for asymmetric catalysis: Readily available carbohydrate-derived diarylphosphinites induce high selectivity in the hydrovinylation of styrene derivatives

Only a limited number of ligands have been successfully employed for the Ni-catalyzed asymmetric hydrovinylation reaction. Diarylphosphonites prepared from readily available carbohydrates in conjunction with a highly dissociated counterion ([3,5-(CF3