1692-53-1Relevant academic research and scientific papers
New and convenient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic organic compounds
Ait-Mohand, Samia,Dolbier Jr., William R.
, p. 3013 - 3015 (2002)
(figure presented) Use of Et3B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF5Cl in high yield to a variety of alkenes and alkynes.
A convenient and efficient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic compounds
Dolbier Jr., William R.,A?t-Mohand, Samia,Schertz, Tyler D.,Sergeeva, Tatiana A.,Cradlebaugh, Joseph A.,Mitani, Akira,Gard, Gary L.,Winter, Rolf W.,Thrasher, Joseph S.
, p. 1302 - 1310 (2008/09/17)
Both SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature, although the SF5Br chemistry is somewha
Synthesis of SF5-benzene (SF5C6 H5 by the SF5-halide method
Winter, Rolf W.,Gard, Gary L.
, p. 549 - 552 (2007/10/03)
Several significant and useful syntheses of pentafluorothiobenzene (SF5C6H5) from SF5-halides (SF5X, X=Cl, Br) and cyclohexene or derivatives of cyclohexene are presented.
