16936-59-7

Upstream product

• 75-62-7 Bromotrichloromethane 
• 23974-72-3 sodium phenylselenide 
• 67-66-3 chloroform 
• 1666-13-3 diphenyl diselenide 
• 17697-12-0 benzeneseleninic anhydride 
• 574-61-8 benzophenone N-phenylhydrazone 

Downstream Products

• 197454-96-9 [2,2-Dimethyl-1-(2,2,2-trichloro-ethyl)-propylselanyl]-benzene 
• 197454-95-8 [1-(2,2,2-Trichloro-ethyl)-heptylselanyl]-benzene 
• 197455-06-4 (1-tert-Butyl-3,3-dichloro-allylselanyl)-benzene 
• 197455-05-3 [1-(2,2-Dichloro-vinyl)-heptylselanyl]-benzene 
• 197455-07-5 (1-Butyl-2-dichloromethylene-hexylselanyl)-benzene 

Relevant academic research and scientific papers

The free-radical addition of phenyl trichloromethyl selenide to alkenes: A new method for the regioselective carboxylation of alkenes

The free-radical addition of phenyl trichloromethyl selenide to alkenes affords 2-phenylseleno-1-trichloromethylalkanes, which can be converted into α,β-unsaturated carboxylic acids or amides by base-promoted dehydrochlorination, followed by [2,3]sigmatropic rearrangement of the corresponding selenoxides in the presence of water or diethylamine, respectively.

On The Reactions of Benzeneseleninic Anhydride With Monosubstituted Hydrazones. Evidence for Radical Pathways.

The known oxidation of mono-substituted hydrazones by benzeneseleninic anhydride has been studied using 77Se and 13C NMR spectroscopy.The intermediates in the reaction have been identified.Good evidence that certain steps in these reactions are radical in character has been secured.