17003-75-7Relevant articles and documents
Polynitroethyl- and fluorodinitroethyl substituted boron esters
Klapoetke, Thomas M.,Krumm, Burkhard,Moll, Richard
, p. 12113 - 12123 (2013)
The reaction of boron oxide with various nitro-substituted ethanols (2-nitroethanol, 2-fluoro-2,2-dinitroethanol, 2,2,2-trinitroethanol) furnished the corresponding nitroethyl borates B(OCH2CH2NO 2)3 (1), B(OCH2CF(NO2) 2)3 (2), and B(OCH2C(NO2) 3)3 (3). Fluorination of the anion [(NO2) 2CCH2OH]- (4) resulted in 2-fluoro-2,2- dinitroethanol (5), a precursor for 2, and was thoroughly characterized. An interesting condensation was observed with the anion 4 to form the unusual dianion [(NO2)2CCH2C(NO2) 2]2- (6). All compounds were fully characterized by multinuclear NMR spectroscopy, vibrational spectroscopy (IR, Raman), mass spectrometry and elemental analysis. The chemical, physical and energetic properties of 1-3 and 5 are reported, as well as quantum chemical calculations at the CBS-4M level of theory to predict the enthalpies and energies of formation. X-ray diffraction studies were performed, and the crystal structures for compounds 1-6 were determined and discussed thoroughly. The boron esters 1-3 are of interest as possible candidates for smoke-free, green colorants in pyrotechnic applications, and in case of 2 and 3 also as promising high energy oxidizers. Copyright
REACTION OF 2-FLUORO-2,2-DINITROETHYLSULFURIC ACID WITH α-HYDROXYCARBOXYLIC ACIDS AND SOME OF THEIR DERIVATIVES
Oreshko, G. V.,Fadeev, M. A.,Eremenko, L. T.
, p. 1021 - 1023 (1983)
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Strukov,G.V. et al.
, (1971)
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SOLID-PHASE FLUORINATION OF SALTS OF NITRO COMPOUNDS
Fokin, A. V.,Radchenko, V. P.,Galakhov, V. S.,Stolyarov, V. P.
, p. 1202 - 1204 (2007/10/02)
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