7182-87-8Relevant academic research and scientific papers
CHEMICAL GENERATION OF TRINITROMETHYL RADICALS IN THE REACTION OF XENON DIFLUORIDE WITH THE NITROFORM ANION
Tselinskii, I. V.,Mel'nikov, A. A.,Trubitsin, A. E.
, p. 619 - 622 (2007/10/02)
In the reaction between the trinitromethane potassium salt and xenon difluoride in acetonitrile in the presence of benzene and THF the trinitromethyl derivatives of benzene and THF are formed in addition to the fluorination products.This indicates that the reaction takes place through the formation of trinitromethyl radicals.
Pressure-Induced Cyclotrimerization of Electron-Deficient Nitriles. Catalysis by Acidic Alcohols and Phenols
Koppes, William M.,Adolph, Horst G.
, p. 406 - 412 (2007/10/02)
Fluorodinitroacetonitrile (1) was pressurized at 1 GPa in the presence of a variety of ROH catalysts.Cyclotrimerization of 1 occurred in several cases, but the observed triazines contained RO groups in place of one or several CF(NO2)2 groups.Some mechanistic aspects of this reaction are explored by comparison with the results of the pressurization of preformed fluorodinitroacetimidates.
