17004-42-1

Basic information

• Product Name: Disulfide, bis[(4-methoxyphenyl)methyl]
• CAS NO: 17004-42-1
• Molecular Formula: C16H18O2S2
• Molecular Weight: 306.45
• Mol File: 17004-42-1.mol
• Article Data: 39

Chemical Properties

• CAS DataBase Reference: Disulfide, bis[(4-methoxyphenyl)methyl](CAS DataBase Reference)
• NIST Chemistry Reference: Disulfide, bis[(4-methoxyphenyl)methyl](17004-42-1)
• EPA Substance Registry System: Disulfide, bis[(4-methoxyphenyl)methyl](17004-42-1)

Safety Data

• Hazardous Substances Data: 17004-42-1(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 64-17-5 ethanol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 19927-28-7 p-methoxybenzyl thiocyanate 
• 68-12-2 N,N-dimethyl-formamide 
• 105-13-5 4-Methoxybenzyl alcohol 
• 126918-29-4 2-chloro-1-(4-chlorophenyl)propan-1-one 
• 6258-60-2 p-methoxybenzylmercaptan 
• 81112-09-6 2-chloro-1-(4-fluorophenyl)propan-1-one 
• 14313-57-6 α-Chlor-n-butyrophenon 
• 456-03-1 1-(4-fluorophenyl)propan-1-one 
• 104-93-8 p-methylanizole 
• 532-27-4 1-chloroacetophenone 
• 106-95-6 allyl bromide 

Downstream Products

• 124667-81-8 1-[(2R,4S,5R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-5-(4-methoxy-benzylsulfanyl)-1H-pyrimidine-2,4-dione 
• 1657-55-2 1,2-bis(4-methoxyphenyl)ethane 
• 6265-92-5 2-(4-methoxy-phenyl)-benzothiazole 
• 34106-64-4 bis(4-methoxybenzyl) sulfide 
• 2620-84-0 2-(4-methoxyphenyl)-1-phenyl-1H-benzo[d]imidazole 
• 1642135-22-5 C₁₃H₂₀OS₂ 
• 1450634-88-4 C₂₁H₂₈N₂O₃S 
• 1450635-17-2 7-methoxy-2-(4-methoxyphenyl)thieno[3,2-b]pyridin-3-ol 
• 1256917-24-4 3-[1-methoxy-4-(4-methoxy-benzylsulfanyl)-piperidin-4-yl]-3-oxo-2-(2,4,6-trimethyl-phenyl)-propionic acid methyl ester 

Relevant articles and documents

Hexamethyldisilazane (HMDS) promotes highly efficient oxidative coupling of thiols by DMSO under nearly neutral reaction conditions

A variety of thiols were efficiently converted to their disulfides using DMSO in the presence of hexamethyldisilazane (HMDS) under almost neutral reaction conditions. Due to the neutrality of the reaction medium in this protocol, acid sensitive functional groups survived intact.

Synthesis and reactivity of α-sulfenyl-β-chloroenones, including oxidation and Stille cross-coupling to form chalcone derivatives

The synthesis of a range of novel α-sulfenyl-β-chloroenones from the corresponding α-sulfenylketones, via a NCS mediated chlorination cascade, is described. The scope of the reaction has been investigated and compounds bearing alkyl- and arylthio substituents have been synthesised. In most instances, the Z α-sulfenyl-β-chloroenones were formed as the major products, while variation of the substituent at the β-carbon position led to an alteration in stereoselectivity. Stille cross-coupling with the Z α-sulfenyl-β-chloroenones led to selective formation of Z sulfenyl chalcones, while the E α-sulfenyl-β-chloroenones did not react under the same conditions. Oxidation of the Z α-sulfenyl-β-chloroenones was followed by isomerisation, leading to the E α-sulfinyl-β-chloroenones. Stille cross-coupling with the E α-sulfinyl-β-chloroenones produced the E sulfinyl chalcones. Either the E or Z sulfinyl chalcones can be obtained by altering the sequence of oxidation and Stille cross-coupling.

Visible-light-responsive lanthanide coordination polymers for highly efficient photocatalytic aerobic oxidation of amines and thiols

Development of visible-light-induced photocatalytic reactions using molecular oxygen as the terminal oxidant is intriguing in view of the current environmental and energy issues. We report herein the synthesis and characterization of a series of novel pho