170080-33-8Relevant academic research and scientific papers
Synthesis of exo- and endo-7,8-epoxyhomotropanes
Justice, David E.,Malpass, John R.
, p. 11947 - 11962 (1996)
Epoxidation of N-protected homotrop-7-ene (9-azabicyclo[4.2.1]non-7-ene) and 1-substituted derivatives occurs stereoselectively from the exo- (β-) face but a practical alternative approach to the exo- epoxides is based on a serendipitous hydride reduction
Stereoselective Oxygenation of the Homotropane Ring System; Synthesis of Exo- and Endo-7-Hydroxy- and 7,8-Epoxyhomotropanes
Justice, David E.,Malpass, John R.
, p. 4685 - 4688 (2007/10/02)
Stereoselective introduction of an endo- epoxide into the 2-carbon bridge of the homotropane (9-azabicyclononane) ring system has been achieved via a 4-aminocyclooct-2-enol derivative; the direct route to the exo- analogue from 7,8-dehydrohomotropa
