170277-50-6Relevant articles and documents
α-Chloroalkylmagnesium reagents of >90% ee by sulfoxide/magnesium exchange
Hoffmann, Reinhard W.,Nell, Peter G.
, p. 338 - 340 (2007/10/03)
Not only for ligand exchange at sulfoxides can the sulfoxide/magnesium exchange reaction be used, but it also provides a possibility to generate Grignard reagents in way that avoids metallic magnesium and thus radical processes. Therefore, enantiomerically pure Grignard reagents can be obtained from the corresponding sulfoxides [Eq. (a)].
A NOVEL SYNTHESIS OF EPOXIDES AND ALLYLIC ALCOHOLS FROM CARBONYL COMPOUNDS THROUGH α,β-EPOXY SULFOXIDES
Satoh, Tsuyoshi,Kaneko, Youhei,Yamakawa, Koji
, p. 2379 - 2382 (2007/10/02)
Treatment of α,β-epoxy sulfoxides, easily prepared from carbonyl compounds with 1 equivalent of n-butyllithium at -100 deg C gave the desulfinated epoxides in good yields.The similar α,β-epoxy sulfoxides having arylmethyl group at α-position, on treatment
