170472-51-2

Basic information

• Product Name: [ReH₄(PPh₃)4][ReO(SC₆H₂Pr(i)3-2,4,6)4]
• CAS NO: 170472-51-2
• Molecular Weight: 2383.26
• Mol File: 170472-51-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [ReH₄(PPh₃)4][ReO(SC₆H₂Pr(i)3-2,4,6)4](CAS DataBase Reference)
• NIST Chemistry Reference: [ReH₄(PPh₃)4][ReO(SC₆H₂Pr(i)3-2,4,6)4](170472-51-2)
• EPA Substance Registry System: [ReH₄(PPh₃)4][ReO(SC₆H₂Pr(i)3-2,4,6)4](170472-51-2)

Safety Data

• Hazardous Substances Data: 170472-51-2(Hazardous Substances Data)

Upstream product

• 12104-75-5 pentahydridotris(triphenylphosphane)Re(V) 
• 22693-41-0 2,4,6-Triisopropylthiophenol 

Relevant articles and documents

Syntheses and Structures of , , (L = N2 or CO) and

The hydride reacted with 2,6-dimethylbenzenethiol in toluene to give a complex of stoichiometry 1.A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate methyl occupying an apical site, trans to the PPh3 ligand.Complex 1 reacts rapidly with MeCN to give the known 2 and with t-BuNC to form 3.The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asymmetric co-ordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups.The reactions of the hydrides and with 2,4,6-triisopropyl-, 2,6-dimethoxy-benzenethiol and tris(2-sulfanylphenyl)phosphine were also studied.With HSC6H2(i-Pr)3-2,4,6 the dinitrogen complex 4 was formed and its structure determined.The preparations and structures of the complexes , 3(PPh3)> and (PPh3)> are also discussed.An alternative convenient route to (+) from is presented.