17054-75-0

Basic information

• Product Name: dibenzo<1,4>dioxin-2-carboxylic acid
• Synonyms: dibenzo<1,4>dioxin-2-carboxylic acid
• CAS NO: 17054-75-0
• Molecular Weight: 228.204
• Mol File: 17054-75-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dibenzo<1,4>dioxin-2-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzo<1,4>dioxin-2-carboxylic acid(17054-75-0)
• EPA Substance Registry System: dibenzo<1,4>dioxin-2-carboxylic acid(17054-75-0)

Safety Data

• Hazardous Substances Data: 17054-75-0(Hazardous Substances Data)

Upstream product

• 39227-54-8 2-chlorodibenzo-p-dioxin 
• 124-38-9 carbon dioxide 

Relevant articles and documents

Electrocarboxylation of chlorinated aromatic compounds

Chorinated benzenes (1, 4), biphenyls (6, 9), dibenzofurans (10, 15, 17, 18), 2-chlorodibenzo[1,4]dioxine (24) and 1-chloronaphthalene (26) as well as dibenzofuran (12) and naphthalene (27) themselves were transformed into carboxylic acids by galvanostatic electroreduction in the presence of carbon dioxide ("electrocarboxylation"). Dry DMF was used as solvent, zinc or stainless steel as cathode and magnesium as a sacrificial anode in an undivided cell. Hydrogenation of aromatic rings was not observed. However, reductive addition of two molecules of carbon dioxide to form dihydrodicarboxylic acids, e.g. 22 and 29, occurs in the dibenzofuran and naphthalene series.