17113-76-7Relevant academic research and scientific papers
Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones
Lian, Chang,Yue, Guanglu,Mao, Jinshan,Liu, Danyang,Ding, Yi,Liu, Zerong,Qiu, Di,Zhao, Xia,Lu, Kui,Fagnoni, Maurizio,Protti, Stefano
supporting information, p. 5187 - 5191 (2019/07/03)
The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.
REGIOSPECIFIC SYNTHESIS OF AROMATIC COMPOUNDS VIA ORGANOMETALLIC INTERMEDIATES. II. 1,3,5-(TRIMETHYLMETAL(IV))BENZENE COMPOUNDS
Chen, Grace J.,Tamborski, Christ
, p. 149 - 158 (2007/10/02)
Sequential metal-halogen exchange reactions between n-C4H9Li and 1,3,5-tribromobenzene and reaction at each step with (CH3)3MIVCl(MIV = Si, Ge, Sn) has provided a 1,3,5-(trimethylmetal(IV))benzene compound.This class of compounds can be synthesized either trough a step-wise procedure, where the various intermediates are isolated, or in a continuous metal-halogen exchange process without isolation of various intermediates.
