171193-54-7Relevant academic research and scientific papers
Synthesis and Transformations of Hydroxy Acetals
Kruglikova, R. I.,Kharitonova, O. V.,Alieva, Z. M.,Arshava, B. M.
, p. 78 - 82 (2007/10/03)
Reactions of 4,4-diethoxy-2-butanone, 2-(diethoxymethyl)cyclohexanone, and 1,1,5,5-tetraethoxy-3-pentanone with alkylmagnesium halides lead to formation of hydroxy acetals: 2-alkyl-4,4-diethoxy-2-butanols, 1-alkyl-2-(diethoxymethyl)cyclohexanols, and 3-alkyl-1,1,5,5-tetraethoxy-3-pentanols, respectively.Specific conditions for these reactions have been determined.Pentamethine salts with alkyl substituents (methyl, ethyl, octyl, dodecyl, hexadecyl, octadecyl) in the polymethine chain have been prepared by aminoformylation of the obtained hydroxy acetals.
