17123-02-3

Upstream product

• 71-23-8 propan-1-ol 
• 41255-51-0 Phosphorsaeure-(8-chinolyl)-phenylester 
• 110-80-5 2-ethoxy-ethanol 
• 38299-59-1 phosphoric acid phenyl ester-dipropyl ester 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 770-12-7 O-phenyl phosphorodichloridate 
• 32599-82-9 diammonium salt of phenyl phosphatosulfate 
• 27460-01-1 n-propyl diphenyl phosphate 

Relevant academic research and scientific papers

Mg2+-Promoted P-O vs. S-O Bond Cleavage in the Alcoholyses of Phenyl Phosphatosulfate

In order to obtain insight into the selectivity of Mg2+ at the site of bond cleavage of P-O and S-O of the P-O-S linkage, metal ion-promoted alcoholyses of phenyl phosphatosulfate were studied.Mg2+ quantitatively promoted P-O bond cleavage in the methanolysis, but mixed cleavage of the P-O bond, which occurred partly due to hydrolysis by trace water and the S-O bond in the reaction of ethanol, 1- or 2-propanol.The ratio of the S-O bond cleavage against the mixed cleavage increased in a order EtOH (11.5percent) 2+ and Zn2+ promoted selective P-O and S-O bond cleavage, respectively, in the reaction of 2-propanol as well as methanolysis.The medium-dependent change in the selectivity of Mg2+ at the site of bond cleavage was discussed.