17146-06-4Relevant articles and documents
Activator-free palladium-catalyzed silylation of aryl chlorides with silylsilatranes
Yamamoto, Yutaro,Matsubara, Hiroshi,Murakami, Kei,Yorimitsu, Hideki,Osuka, Atsuhiro
, p. 219 - 224 (2015)
The palladium-catalyzed silylation of aryl chlorides with silylsilatranes proceeds under activator-free conditions; hence, wide functional group compatibility is displayed and boryl and siloxy groups are able to survive. Experimental and computational stu
Nickel-Catalyzed Selective Cross-Coupling of Chlorosilanes with Organoaluminum Reagents
Naganawa, Yuki,Guo, Haiqing,Sakamoto, Kei,Nakajima, Yumiko
, p. 3756 - 3759 (2019/09/12)
Nickel-catalyzed cross-coupling reactions of chlorosilanes with organoaluminum reagents were developed. An electron-rich Ni(0)/PCy3 complex was found to be an effective catalyst for the desired transformation. The reaction of dichlorosilanes 1 proceeded to give the corresponding monosubstituted products 2. Trichlorosilanes 4 underwent selective double substitution to furnish the corresponding monochlorosilanes 2. Overall, the selective synthesis of a series of alkylmonochlorosilanes 2 from di- and trichlorosilanes was achieved using the present catalytic systems.
ISOMERIZATION OF CHLOROMETHYLALKENYL- AND CHLOROMETHYLPHENYLSILANES
Zhun', V. I.,Ustinova, O. L.,Sheludyakov, V. D.,Turkel'taub, G. N.,Slyusarenko, T. F.,et al.
, p. 986 - 990 (2007/10/02)
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