17186-52-6

Upstream product

• 149182-70-7 N²-<(tert-butoxy)carbonyl>-L-phenylalanine tert-butylamide 
• 13734-34-4 N-tert-butoxycarbonyl-L-phenylalanine 
• 126402-91-3 2,2-Dimethyl-propionic acid (2S,3S,4R,5R)-2-[((S)-1-tert-butylcarbamoyl-2-phenyl-ethyl)-formyl-amino]-4,5-bis-(2,2-dimethyl-propionyloxy)-tetrahydro-pyran-3-yl ester 

Downstream Products

• 63-91-2 L-phenylalanine 
• 251339-76-1 {4-[acetyl-(1(S)-tert-butylcarbamoyl-2-phenylethyl)amino]-1(S)-benzyl-2(R,S)-acetoxybutyl}carbamic acid tert-butyl ester 

Relevant academic research and scientific papers

Inducing Enantioselectivity in a Dynamic Catalyst by Supramolecular Interlocking

The design of a new class of fluxional biphenyl bisphosphinite (BIBIPHOS) ligands decorated with amino acid-based diamide interaction sites is reported that undergo spontaneous desymmetrization. Hydrogenation of prochiral alkenes using Rh-BIBIPHOS results

Supramolecular Interlocked Biphenyl Ligands for Enantioselective Ti-Catalyzed Alkylation of Aromatic Aldehydes

The substitution of tropos 2,2′-biphenols with (S)-amino-acid-derived interaction sites in the 5,5′-position results in a spontaneous desymmetrization. This process is driven by well-defined intermolecular hydrogen bonding, which leads to diastereoselecti

Cleavage of unactivated amide bonds by ammonium salt-accelerated hydrazinolysis

Hydrazinolysis of unactivated amide bonds is significantly accelerated by the addition of ammonium salts. The reactions proceed at 50-70 °C to give amines with broad substrate scope that outperforms existing amide bond cleavage reactions. Application to peptide and amino sugar derivatives is also demonstrated. This journal is

Stereoselective synthesis of L-amino acids via Strecker and Ugi reactions on carbohydrate templates

L-Amino acid derivatives are stereoselectively synthesized in high yield using 2,3,4-tri-O-pivaloyl-α-D-arabinopyranosylamine or 2,3,4-tri-O-pivaloyl-β-L-fucopyranosylamine as the chiral auxiliary in Strecker and Ugi reactions.