171881-79-1Relevant articles and documents
Total Synthesis of Alloviroidin
Taylor, Carol M.,Kutty, Samuel K.,Edagwa, Benson J.
, p. 2281 - 2284 (2019)
Alloviroidin is a cyclic heptapeptide, produced by several species of Amanita mushrooms, that demonstrates high affinity for F-actin as is characteristic of virotoxins and phallotoxins. Alloviroidin was synthesized via a [3 + 4] fragment condensation of F
Enantioselective synthesis of anti-β-substituted γ,δ- unsaturated amino acids: A highly selective asymmetric thio-Claisen rearrangement
Liu, Zhihua,Qu, Hongchang,Gu, Xuyuan,Min, Byoung J.,Nyberg, Joel,Hruby, Victor J.
supporting information; experimental part, p. 4105 - 4108 (2009/05/30)
(Chemical Equation Presented) A novel synthesis of optically active anti-β-substituted γ,δ-unsaturated amino acids via a thio-Claisen rearrangement has been achieved. A 2,5-diphenylpyrrolidine was used as a (C2-symmetric chiral auxiliary to control the stereochemistry, giving good yields and excellent diastereoselectivities and enantioselectivities.
