172288-33-4Relevant articles and documents
Bond-Weakening Catalysis: Conjugate Aminations Enabled by the Soft Homolysis of Strong N-H Bonds
Tarantino, Kyle T.,Miller, David C.,Callon, Ted A.,Knowles, Robert R.
supporting information, p. 6440 - 6443 (2015/06/08)
The ability of redox-active metal centers to weaken the bonds in associated ligands is well precedented, but has rarely been utilized as a mechanism of substrate activation in catalysis. Here we describe a catalytic bond-weakening protocol for conjugate a
One-pot curtius rearrangement processes from carboxylic acids
Leogane, Olivier,Lebel, Helene
scheme or table, p. 1935 - 1940 (2009/12/29)
An efficient and practical synthesis of amine derivatives from carboxylic acids is described using new one-pot Curtius rearrangement processes. The preparation of carbamate-protected amines and anilines, as well as ureas was achieved in good to excellent yields on a multigram scale. Georg Thieme Verlag Stuttgart.
Preparation and Reactivity of Allyl N-carbamates, New Reagents for Electrophilic Transfer of an NHAlloc Group
Greck, C.,Bischoff, L.,Ferreira, F.,Genet, J. P.
, p. 7010 - 7012 (2007/10/03)
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