10364-93-9

Basic information

• Product Name: 1H-Imidazole, 1-(4-methoxybenzoyl)-
• CAS NO: 10364-93-9
• Molecular Formula: C11H10N2O2
• Molecular Weight: 202.213
• Mol File: 10364-93-9.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: 1H-Imidazole, 1-(4-methoxybenzoyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Imidazole, 1-(4-methoxybenzoyl)-(10364-93-9)
• EPA Substance Registry System: 1H-Imidazole, 1-(4-methoxybenzoyl)-(10364-93-9)

Safety Data

• Hazardous Substances Data: 10364-93-9(Hazardous Substances Data)

Upstream product

• 288-32-4 1H-imidazole 
• 100-07-2 4-methoxy-benzoyl chloride 
• 100-09-4 4-methoxybenzoic acid 
• 530-62-1 1,1'-carbonyldiimidazole 
• 16778-84-0 4-methoxybenzoyl isothiocyanate 
• 130838-42-5 4',5'-Dihydro-1'H-[1,2']biimidazolyl 

Downstream Products

• 33207-59-9 2-(4'-methoxybenzoyl)fluorene 
• 27918-36-1 1-(4-methoxyphenyl)-2-(methylsulfonyl)-1-ethanone 
• 132164-97-7 [3-(4-Methoxy-benzoyl)-2,3-dihydro-imidazol-1-yl]-(4-methoxy-phenyl)-methanone 
• 50622-93-0 3'-O-anisoyluridine 
• 50796-34-4 2'-O-anisoyluridine 
• 121379-18-8 5'-O-anisoyluridine 
• 50796-29-7 2'-O-anisoyladenosine 
• 50796-30-0 3'-O-anisoyladenosine 
• 46318-58-5 4-methoxybenzoylnitromethane 
• 1196665-95-8 [4-(methyloxy)phenyl][(1S,2S)-2-(4-methylphenyl)-1-nitrocyclopropyl]methanone 
• 1196665-98-1 {(1S,2S)-2-[4-(1,1-dimethylethyl)phenyl]-1-nitrocyclopropyl}[4-(methyloxy)phenyl]methanone 
• 1196666-01-9 ((1S,2S)-(Z)-2-(4-chlorophenyl)-1-nitrocyclopropyl)(4-methoxyphenyl)methanone 
• 1196666-03-1 ((1S,2S)-(Z)-2-(4-fluorophenyl)-1-nitrocyclopropyl)(4-methoxyphenyl)methanone 
• 1196666-04-2 (4-methoxyphenyl)((1S,2S)-(Z)-1-nitro-2-(4-nitrophenyl)cyclopropyl)methanone 

Relevant articles and documents

Chemoselective acylation of 2-amino-8-quinolinol in the generation of C2-amides or C8-esters

Two different ways to carry out the chemoselective acylation of 2-amino-8-quinolinol with unique features to generate C2-amides or C8-esters were developed. The coupling reaction with a variety of carboxylic acids using EDCI and DMAP provided C8-ester derivatives, whereas N-heteroaromatic acids were not introduced on the C8-hydroxy group, but rather on the C2-amino group under the same conditions. To obtain C2-amides selectively, the anionic nucleophile from 2-amino-8-quinolinol was treated with less reactive acyl imidazolides or esters.

Combined Photoredox and Carbene Catalysis for the Synthesis of γ-Aryloxy Ketones

N-heterocyclic carbenes (NHCs) have emerged as catalysts for the construction of C?C bonds in the synthesis of substituted ketones under single-electron processes. Despite these recent reports, there still remains a need to increase the utility and practicality of these reactions by exploring new radical coupling partners. Herein, we report the synthesis of γ-aryloxyketones via combined NHC/photoredox catalysis. In this reaction, an α-aryloxymethyl radical is generated via oxidation of an aryloxymethyl potassium trifluoroborate salt, which is then added into styrene derivatives to provide a stabilized benzylic radical. Subsequent radical-radical coupling reaction with an azolium radical affords the γ-aryloxy ketone products. (Figure presented.).

Silver-Catalyzed Acyl Nitrene Transfer Reactions Involving Dioxazolones: Direct Assembly of N-Acylureas

Dioxazolones and isocyanides are useful synthetic building blocks, and have attracted significant attention from researchers. However, the silver-catalyzed nitrene transfer reaction of dioxazolones has not been investigated to date. Herein, a silver-catalyzed acyl nitrene transfer reaction involving dioxazolones, isocyanides, and water was realized in the presence of Ag2O to afford a series of N-acylureas in moderate to good yields.

BASE CONVERSION PROLIFERATOR

PROBLEM TO BE SOLVED: To provide a photocurable composition with sufficient curability employing a photobase generator. SOLUTION: A base conversion proliferator comprises a compound represented by the specified general formula (1). The base conversion pro